Observations of low mean metallicity of damped Lyα (DLA) quasar absorbers at all redshifts studied appear to contradict the predictions for the global mean interstellar metallicity in galaxies from cosmic chemical evolution models. On the other hand, a number of metal-rich sub-DLA systems have been identified recently, and the fraction of metal-rich sub-DLAs appears to be considerably larger than that of metal-rich DLAs, especially at z < 1.5. In view of this, here we investigate the evolution of metallicity in sub-DLAs. We find that the mean Zn metallicity of the observed sub-DLAs may be higher than that of the observed DLAs, especially at low redshifts, reaching a near-solar level at z 1. This trend does not appear to be an artifact of sample selection, the use of Zn, the use of NH i weighting, or observational sensitivity. While a bias against very low metallicity could be present in the sub-DLA sample in some situations, this cannot explain the difference between the DLA and sub-DLA metallicities at low z. The primary reason for the difference between the DLAs and sub-DLAs appears to be the dearth of metal-rich DLAs. We estimate the sub-DLA contribution to the total metal budget using measures of their metallicity and comoving gas density. These calculations suggest that at z 1, the contribution of sub-DLAs to the total metal budget may be several times that of DLAs. At higher redshifts also, there are indications that the sub-DLAs may contribute significantly to the cosmic metal budget.

We have reanalyzed the existing data on Zinc abundances in damped Ly-alpha (DLA) absorbers to investigate whether their mean metallicity evolves with time. Most models of cosmic chemical evolution predict that the mass- weighted mean interstellar metallicity of galaxies should rise with time from a low value ~ 1/30 solar at z ~ 3 to a nearly solar value at z ~ 0. However, several previous analyses have suggested that there is little or no evolution in the global metallicity of DLAs. We have used a variety of statistical techniques to quantify the global metallicity-redshift relation and its uncertainties, taking into account both measurement and sampling errors. Three new features of our analysis are: (a) an unbinned N(H I)-weighted nonlinear chi-square fit to an exponential relation; (b) survival analysis to treat the large number of limits in the existing data; and (c) a comparison of the data with several models of cosmic chemical evolution based on an unbinned N(H I)-weighted chi-square. We find that a wider range of evolutionary rates is allowed by the present data than claimed in previous studies. The slope of the exponential fit to the N(H I)-weighted mean Zn metallicity vs. redshift relation is -0.20 plus minus 0.11 counting limits as detections and -0.27 plus minus 0.12 counting limits as zeros. Similar results are also obtained if the data are binned in redshift, and if survival analysis is used. These slopes are marginally consistent with no evolution, but are also consistent with the rates predicted by several models of cosmic chemical evolution. Finally, we outline some future measurements necessary to improve the statistics of the global metallicity-redshift relation.Comment: 25 pages, 1 figure, accepted for publication in the Astrophysical Journa

Measurements of element abundances in galaxies from astrophysical spectroscopy depend sensitively on the atomic data used. With the goal of making the latest atomic data accessible to the community, we present a compilation of selected atomic data for resonant absorption lines at wavelengths longward of 911.753 Å (the H i Lyman limit), for key heavy elements (heavier than atomic number 5) of astrophysical interest. In particular, we focus on the transitions of those ions that have been observed in the Milky Way interstellar medium (ISM), the circumgalactic medium (CGM) of the Milky Way and/or other galaxies, and the intergalactic medium (IGM). We provide wavelengths, oscillator strengths, associated accuracy grades, and references to the oscillator strength determinations. We also attempt to compare and assess the recent oscillator strength determinations. For about 22% of the lines that have updated oscillator strength values, the differences between the former values and the updated ones are ≳0.1 dex. Our compilation will be a useful resource for absorption line studies of the ISM, as well as studies of the CGM and IGM traced by sight lines to quasars and gamma-ray bursts. Studies (including those enabled by future generations of extremely large telescopes) of absorption by galaxies against the light of background galaxies will also benefit from our compilation.

We present elemental abundance measurements for nine damped Lyman α (Lyα) systems (DLAs) and one sub-DLA at 0.1 ≲z≲ 1.5 from recent observations with