Hydrogen, with its high energy density and zero greenhouse gas emissions, is an exceptional energy vector, pivotal for a sustainable energy future. Ammonia, serving as a practical and cost-effective hydrogen carrier, offers a secure method for hydrogen storage and transport. The decomposition of ammonia into hydrogen is a crucial process for producing green hydrogen, enabling its use in applications ranging from clean energy generation to fueling hydrogen-powered vehicles, thereby advancing the transition to a carbon-free energy economy. This study investigates the catalytic performance of various 3D-printed porous supports based on periodic open cellular structures (POCS) and triply periodic minimal surface (TPMS) architecture manufactured from IN625 nickel alloy powder using the laser powder bed fusion (LPBF) technique. The POCS and TPMS, featuring geometries including BCC, Kelvin, and Gyroid, were analyzed for cell size, strut/sheet diameter, porosity, and specific surface area. Pressure drop analyses demonstrated correlations between structural parameters and fluid dynamics, with BCC structures exhibiting lower pressure drops due to their higher porosity and the open channel network. The dip/spin coating method was successfully applied to activate the supports with a commercial Ru/Al₂O₃ catalyst, achieving uniform coverage crucial for catalytic performance. Among the tested geometries, the Gyroid structure showed superior catalytic activity towards ammonia decomposition, attributed to its efficient mass transfer pathways. This study highlights the importance of structural design in optimizing catalytic processes and suggests the Gyroid structure as a promising candidate for improving reactor efficiency and compactness in hydrogen production systems.

Additive Manufacturing (AM) of parts used in nuclear power plants can solve many issues like those related to obsolescence. Of the gap limiting the use of AM parts in nuclear is the need of reliable non-destructive inspection capable to meet the qualification requirements. Recently, efforts in this direction have been made worldwide within several research projects, like the EU Horizon 2020 NUCOBAM. In the framework of NUCOBAM, this article presents the activity related to the inspection of 316-L AM nuclear parts produced by L-PBF and inspected via advanced ultrasonic (UT) methods, like MultiPoint Focusing (MPF) and Total Focusing Method (TFM). Multiple UT array probes are used, linear, matrix and annular. Emphasis is dedicated to the inspection of classified valve bodies produced with known internal seeding flaws. The analysis of the results shows the effect of AM induced anisotropy on the propagation of the ultrasonic wave characteristics, the sound velocity increased with 3% when the sound beam deviated 15° against the perpendicular axis. The TFM method contributed significantly regarding defect detection, Signal to Noise Ratios (SNR) increased with at least 9 dB compared to the Multi-Point Focusing method. Smaller errors were noticed when examination frequency was increased and TFM was applied. The combination of an annular array with TFM and mechanical scanning demonstrated to be the best approach.