Fernando Leal-Calderon

Prof. Fernando Leal-Calderon


Research Focus & Metrics

Academic Career Length

34Years (1993-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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1 July 2003 in The European Physical Journal E
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Journal Article
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SAS. Arditty
S. Arditty
CWCatherine Whitby
Catherine Whitby
BBB. P. Binks
B. P. Binks
VSV. Schmitt
V. Schmitt
FLFernando Leal-Calderon
Fernando Leal-Calderon

11 July 2011 in Soft Matter
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Journal Article
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MDMathieu Destribats
Mathieu Destribats
VLVéronique Lapeyre
Véronique Lapeyre
MWMélanie Wolfs
Mélanie Wolfs
ESElisabeth Sellier
Elisabeth Sellier
FLFernando Leal-Calderon
Fernando Leal-Calderon
VSVéronique Schmitt
Véronique Schmitt
We synthesised soft uncharged microgels made of poly(N-isopropylacrylamide) of variable cross-linking degrees and we probed their efficiency as stabilisers to fabricate oil-in-water emulsions. Interestingly, such particles undergo a swollen-to-collapsed transition above a critical temperature. By combining several microscopy methods and by exploiting the limited coalescence process, we were able to determine both the particle concentration and structure at the interface, as a function of the cross-linking density. Being deformable, the initially spherical microgels adopt a “fried egg-like” structure when adsorbed at the oil/water interface. As expected, the interfacial deformation is increasingly pronounced as the cross-linking degree decreases. The most deformable microgels tend to form 2D connected networks characterised by significant overlapping of the peripheral parts. When the deformability is lost, by increasing the cross-linking density or the temperature, the stabilisation efficiency is considerably reduced. Our results strongly suggest that emulsion stability is mainly determined by the microgels' deformability and we discuss the origin of that empirical link in terms of lateral overlapping and interfacial elasticity.

1 January 1999 in Reports on Progress in Physics
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Journal Article
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JBJ Bibette
J Bibette
FLFernando Leal-Calderon
Fernando Leal-Calderon
PPP Poulin
P Poulin

1 August 2008 in Current Opinion in Colloid & Interface Science
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Journal Article
Closed access
FLFernando Leal-Calderon
Fernando Leal-Calderon
VSV. Schmitt
V. Schmitt

1 July 2004 in Journal of Colloid and Interface Science
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Journal Article
Closed access
SAStéphane Arditty
Stéphane Arditty
VSVéronique Schmitt
Véronique Schmitt
JGJoanna Giermanska-Kahn
Joanna Giermanska-Kahn
FLFernando Leal-Calderon
Fernando Leal-Calderon

1 January 2007
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Book
Closed access
FLFernando Leal-Calderon
Fernando Leal-Calderon
JBJérôme Bibette
Jérôme Bibette
VSVéronique Schmitt
Véronique Schmitt