In the present study, nanoscale rod-shaped manganese oxide (MnO) mixtures were successfully prepared from graphitic carbon nitride (C₃N₄) and potassium permanganate (KMnO₄) through a hydrothermal method. The as-prepared MnO nanomixtures exhibited high activity in the adsorption and degradation of methylene blue (MB). The as-synthesized products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), surface area analysis, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Furthermore, the effects of the dose of MnO nanomixtures, pH of the solution, initial concentration of MB, and the temperature of MB removal in dye adsorption and degradation experiments was investigated. The degradation mechanism of MB upon treatment with MnO nanomixtures and H₂O₂ was studied and discussed. The results showed that a maximum adsorption capacity of 154 mg g⁻¹ was obtained for a 60 mg L⁻¹ MB solution at pH 9.0 and 25 °C, and the highest MB degradation ratio reached 99.8% under the following optimum conditions: 50 mL of MB solution (20 mg L⁻¹) at room temperature and pH ≈ 8.0 with 7 mg of C, N-doped MnO and 0.5 mL of H₂O₂.

Circularly polarized luminescence (CPL) of chiral materials responsive to external stimuli has drawn widespread attention due to their important applications in smart photonic materials. Here, a CPL‐active chiral emitter derived from guanidine‐substituted 1,8‐naphthalimide (R/S‐1) is reported, which could emit tunable circularly polarized light through regulating the situation of protonation/deprotonation in aqueous, as well as the solvent polarity. Tunable fluorescence emission from the protonated compound can be observed, which is contributed to excited‐state proton transfer of guanidine moiety, as well as the intramolecular charge transfer of naphthalimide group. Subsequently, color‐tunable CPL is obtained, enabling a single‐molecule‐white‐color circularly polarized light emission. Additionally, by introducing R/S‐1 into chiral nematic liquid crystal film, CPL emission is adjusted by exposing to acid/alkaline environment, which can be directly distinguished by naked eyes due to the extremely large dissymmetry factor (|g_lum| = 1.1). This work opens new venues for photonic applications of CPL active materials.

In this paper, different metal-doped carbon aerogels are prepared by one-step carbonization with sodium alginate as raw material. It was known by SEM and TEM that the metal was uniformly dispersed into the carbon aerogels. Cr-doped carbon aerogel has a rich pore structure with a specific surface area of up to 497.4 m² g^-1. The prepared samples were used in the field of supercapacitors, and the test results showed that the Cr-doped carbon aerogel has the highest specific capacitance (312.5 F g^-1).This study not only develops new directions for the utilization of marine biomass resources, but also provides a simple method for preparing metal-doped carbon material.

Environmental problems caused by metal ions have caused widespread concern in recent years. In this work, carbon aerogels (CAs) adsorbing different metal ions were prepared. The adsorption performance and kinetics of metal ions (Cu(II), Cr(VI), and Fe(III)) on carbon aerogels were systematically investigated. The results indicated that the maximum adsorption capacity of Cu(II) was 424 mg·g⁻¹ in 600 mg·L⁻¹ copper solution. Adsorption performances of Cu(II), Cr(VI), and Fe(III) on CAs well fitted with a pseudo-second-order kinetic model. The structures and morphologies of metal-containing samples were characterized by scanning electron micrographs (SEM), Energy Dispersive Spectrometer (EDS), transmission electron microscope (TEM), and X-ray diffraction (XRD). The results demonstrated that the texture and electrochemical performance of CAs adsorbing metal ions exhibited a clear change. The specific surface area of CAs for adsorbing copper ions was 450 m²·g⁻¹ and they showed a small average pore diameter (7.16 nm). Furthermore, CAs adsorbing metals could be used for the super capacitor. The specific capacitance of CAs adsorbing copper ions could reach 255 F·g⁻¹ at a current density of 1.0 A·g⁻¹. The CA-Cu electrode materials exhibited excellent reversibility with a cycling efficiency of 97% after 5000 cycles.

Polycondensation of phloroglucinol, resorcinol and formaldehyde with carbon nanotube (CNT) as the additives, using sodium carbonate as the catalyst, leads to the formation of CNT - doped carbon aerogels. The structure of carbon aerogels (CAs) with carbon nanotubes (CNTs) were characterized by X-ray diffraction and scanning electron microscopy. The specific surface area, pore size distribution and pore volume were measured by surface area analyzer. The results show that when the optimum doping dosage is 5%, the specific surface area of CNT - doped carbon aerogel is up to 665 m² g^-1 and exhibit plentiful mesoporous.