The development of an advanced dye adsorbent that possesses a range of beneficial characteristics, such as high adsorption capacity, swift adsorption kinetics, selective adsorption capability, and robust reusability, remains a challenge. This study introduces a facile method for fabricating an amine-rich porous adsorbent (ARPA), which is specifically engineered for the adsorptive removal of anionic dyes from aqueous solutions. Through a comprehensive assessment, we have evaluated the adsorption performance of ARPA using two benchmark dyes: amaranth (ART) and tartrazine (TTZ). Our findings indicate that the adsorption process reaches equilibrium in a remarkably short timeframe of just 20 min, and it exhibits an excellent correlation with both the Langmuir isotherm model and the pseudo-second-order kinetic model. Furthermore, ARPA has demonstrated an exceptional maximum adsorption capacity, with values of 675.68 mg g−1 for ART and 534.76 mg g−1 for TTZ. In addition to its high adsorption capacity, ARPA has also shown remarkable selectivity, as evidenced by its ability to selectively adsorb TTZ from a mixed dye solution, a feature that is highly desirable for practical applications. Beyond its impressive adsorption capabilities, ARPA can be efficiently regenerated and recycled. It maintains a high level of original removal efficiency for both ART (76.8%) and TTZ (78.9%) even after five consecutive cycles of adsorption and desorption. Considering the simplicity of its synthesis and its outstanding adsorption performance, ARPA emerges as a highly promising material for use in dye removal applications. Consequently, this paper presents a straightforward and feasible method for the production of an effective dye adsorbent for environmental remediation.
The valorization of biomass waste represents an important direction in green chemistry. This study successfully prepared blue fluorescent carbon dots (BP-CDs) from waste banana peels via a one-step hydrothermal method, establishing a dual-functional platform for both pollutant detection and cellular imaging. The resulting material exhibited uniform particle size (~2.05 nm), good water dispersibility, and strong fluorescence emission at 445 nm under 360 nm excitation. It maintained over 93% of its initial fluorescence intensity after 20 days, demonstrating excellent stability. Based on the inner filter effect, the probe enabled a highly selective detection of tetracycline with a detection limit of 0.191 µM and two wide linear ranges (0–15 µM, R2 = 0.996; 15–95 µM, R2 = 0.991). Cellular experiments confirmed the good biocompatibility of BP-CDs (cell viability > 84%) and their successful application in cell imaging. More importantly, the probe achieved visual observation and semi-quantitative analysis of the distribution and content of tetracycline in living cells, providing a direct tool for studying the cellular behavior of antibiotics. This work not only offers a new strategy for banana peel valorization but also develops a green fluorescence imaging platform suitable for tracking intracellular pollutants.
11 April 2025 in International Journal of Biological Macromolecules