In this paper a stationary action principle is proved to hold for capillary fluids, i.e. fluids for which the deformation energy has the form suggested, starting from molecular arguments. We remark that these fluids are sometimes also called Korteweg–de Vries or Cahn–Allen fluids. In general, continua whose deformation energy depends on the second gradient of placement are called second gradient (or Piola–Toupin, Mindlin, Green–Rivlin, Germain or second grade) continua. In the present paper, a material description for second gradient continua is formulated. A Lagrangian action is introduced in both the material and spatial descriptions and the corresponding Euler–Lagrange equations and boundary conditions are found. These conditions are formulated in terms of an objective deformation energy volume density in two cases: when this energy is assumed to depend on either C and ∇ C or on C⁻¹ and ∇ C⁻¹, where C is the Cauchy–Green deformation tensor. When particularized to energies which characterize fluid materials, the capillary fluid evolution conditions are recovered. A version of Bernoulli’s law valid for capillary fluids is found and useful kinematic formulas for the present variational formulation are proposed. Historical comments about Gabrio Piola’s contribution to analytical continuum mechanics are also presented.

In this paper reflection and transmission of compression and shear waves at structured interfaces between second-gradient continua is investigated. Two semi-infinite spaces filled with the same second-gradient material are connected through an interface which is assumed to have its own material properties (mass density, elasticity and inertia). Using a variational principle, general balance equations are deduced for the bulk system, as well as jump duality conditions for the considered structured interfaces. The obtained equations include the effect of surface inertial and elastic properties on the motion of the overall system. In the first part of the paper general 3D equations accounting for all surface deformation modes (including bending) are introduced. The application to wave propagation presented in the second part of the paper, on the other hand, is based on a simplified 1D version of these equations, which we call “axial symmetric” case.