Jakub Plasil

Dr. Jakub Plasil

Department of Structure Analysis, Academy of Sciences of the Czech Republic, Prague, Czech Republic
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Research Focus & Metrics

Academic Career Length

21Years (2006-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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12 April 2014 in Journal of GEOsciences
Verified
Journal Article
Open access
PDF file
JPJakub Plasil
Jakub Plasil

1 October 2016 in Zeitschrift für Kristallographie - Crystalline Materials
Verified
Journal Article
Closed access
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PEPetříček
Petříček
VÁVáclav
Václav
MDMichal Dusek
Michal Dusek
JPJakub Plasil
Jakub Plasil
Twinning is a phenomenon complicating structure analysis of single crystals of standard as well as modulated structures. Jana2006 as a software for advanced structure analysis contains tools for recognition and refinement of twins including most complicated cases of modulated and magnetic structures. In order to efficiently use the tools of Jana2006 related to twinning, we explain the basic terminology and the underlying theory, especially the symmetry of the diffraction patterns affected by twinning. We present typical diffraction patterns of twins and show how twinning can be recognized or detected by various tools and described with twinning matrices. Data processing of twins and ways of how they can be imported to Jana2006 are also discussed. Two examples demonstrate the solution of typical twins: twinning by metric merohedry and twinning by reticular merohedry, followed by the third example demonstrating twinning in a commensurately modulated structure. The relationship between the dimensionality of the structure and twinning is discussed, too.

1 April 2012 in Hydrometallurgy
Verified
Journal Article
Closed access
JMJuraj Majzlan
Juraj Majzlan
PDPetr Drahota
Petr Drahota
MFMichal Filippi
Michal Filippi
KGKlaus-Dieter Grevel
Klaus-Dieter Grevel
WKWolf-Achim Kahl
Wolf-Achim Kahl
BWBrian F. Woodfield
Brian F. Woodfield

1 April 2011 in Journal of Raman Spectroscopy
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Journal Article
Closed access
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RFRay Frost
Ray Frost
SPSara J. Palmer
Sara J. Palmer
JČJiří Čejka
Jiří Čejka
JSJiří Sejkora
Jiří Sejkora
JPJakub Plasil
Jakub Plasil
EKEloise C. Keeffe
Eloise C. Keeffe

3 November 2014 in Environmental Science & Technology
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Journal Article
Closed access
JMJuraj Majzlan
Juraj Majzlan
JPJakub Plasil
Jakub Plasil
RŠRadek Škoda
Radek Škoda
JGJohannes Gescher
Johannes Gescher
FKFelix Kögler
Felix Kögler
JRJörg Rothe
Jörg Rothe

20 August 2018 in European Journal of Mineralogy
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Journal Article
Closed access
JPJakub Plasil
Jakub Plasil
Uranyl-oxide hydroxy-hydrates (UOH) represent one of the most structurally and chemically complex families of naturally occurring U6+ phases.To date, about 28members are known as mineral species and a dozen others have been synthesized under laboratory conditions. The majority of these have been structurally characterized, showing an extraordinary complexity despite their relatively simple chemical composition; U, Pb, O and H are mostly the major constituents. Both the structural and chemical complexity of UOH minerals were determined with the program TOPOS, using complexity parameters that provide Shannon information content per atom and per unit cell and per formula unit.The average content per unit cell,1159 bits/cell shows that UOH minerals are extraordinary complex; this is in line with (1) the high coordination diversity, considering the transition of U4+ to U6+ during oxidation-hydration weathering of uraninite that leads to the formation of UOH phases; (2) incorporation of a large amount of H+, in the form of H2O and (OH)-; (3) incorporation of other elements during weathering,mostly K+, Pb2+ or Ca2+. The simplest UOH mineral is vandenbrandeite, triclinic, Cu (UO2)(OH)4, with 86 bits/cell. The most complex UOH mineral is vandendriesscheite, orthorhombic Pb1.5[(UO2)10O6(OH)11](H2O)11, with 4296 bits/cell, which owes its structural complexity to the presence of a large proportion of H2O/OH and several symmetrically unique U sites in the structure. The general trend of the early-forming UOH minerals is a high molar proportion of U and H2O/OH and lower proportion of metal cations. This leads in general to their complex character. The increase in complexity (both structural and chemical) is also related to the presence of metal cations in the structure with distinct stereochemistry, such asK+, Fe2+, Ca2+ or Pb2+. The overall trend is a steady increase of complexity (both structural and chemical) during continuous alteration. A discussion of occurrence trends and UOH complexity is given. One of the most complex structures among UOHs is schoepite, [(UO2)8O2(OH)12](H2O)12 (∼2593 bits/cell), which is reported from various localities worldwide. The relatively common occurrence of schoepite is probably because it is a very early alteration product, which is (1) complex and (2) easily distinguishable.