In the current era of globalization, synthetic dyes are one of the key factors of water pollution. Photocatalysis constitutes a promising technology for the treatment of wastewater, especially to those containing hard-to-remove organic compounds. Zinc oxide nanoparticles (ZnONPs) play a vital role as a photocatalyst material. This research highlights the synthesized ZnONPs with roselle flower and oil palm leaf extract. The extracts and sodium hydroxide (NaOH) act as reducing agents during the synthesis process. Synthesis without the addition of plant extract is used as blank control for the experiment. Structural and optical studies of the three variants of ZnONPs were performed. High purity of ZnONPs with element Zn and O was obtained. The size of the three variants of ZnONPs was from 10–15 nm and found in agglomerated spherical shape. Large band gap, 3.2 eV was obtained by UV-Vis and high thermal stability was proven by TGA. Oxygen vacancies that assist in the degradation phenomenon were found in ZnONPs. Five percent of ZnONPs with the presence of 10 W UV light could effectively degrade 10 ppm MO in 5 h and MB in 3 h. Besides, high antioxidant properties and low toxicity demonstrated the ability of ZnONPs to be used as photocatalysts. In conclusion, ZnONPs can be further developed for pharmaceutical and industrial use.

Fundamental studies involving divalent ion intercalated graphene-based hydrogel are still lacking in terms of their adsorption behavior towards dye pollutants. In this study, we prepared a self-assembled Mg²⁺ and Ca²⁺ intercalated reduced graphene hydrogel (rGH) using hydrothermal treatment to evaluate the intercalation impact on the adsorption capability towards cationic dyes, methylene blue and rhodamine B. The morphological, structural, thermal, and textural properties of the divalent ion intercalated reduced graphene hydrogels were studied using Fourier transform infrared spectrometer, thermogravimetric analysis, Raman spectroscopy, scanning electron microscope-energy dispersive spectroscopy, X-ray photoelectron spectroscopy, Brunauer–Emmett–Teller surface area analysis, and X-ray diffraction. The increased adsorption capacity of the divalent ion intercalated reduced graphene-based hydrogels towards the dye molecules resulted from the increase in the specific surface area and pore volume due to the Mg²⁺ and Ca²⁺ bridging that formed spaces between the graphene sheets framework. Adsorption kinetics and the equilibrium adsorption isotherm were fitted by a pseudo-second-order alongside intraparticle diffusion kinetic models and Langmuir isotherm respectively. In addition, the divalent ion intercalated reduced graphene hydrogel showed good generation after three cycles of simultaneous adsorption.