Urbanization is an issue that is strongly emerging in southern West Africa (sWA). There is a lack of full understanding on chemical compositions and personal exposure levels to fine particulate matter (hereafter defined as PE PM_2.5) and its health risks related to various anthropogenic sources in this region. In this study, PE PM_2.5 was studied in dry (January) and wet (July) seasons of 2016 for the first time to characterize the contributions of a domestic fire site (DF) to the exposure of women and a waste burning site (WB) to that of students in Abidjan, Côte d'Ivoire, and a motorcycle traffic site (MT) to that of drivers in Cotonou, Benin. The average PE PM_2.5 mass concentrations were 331.7±190.7, 356.9±71.9 and 242.8±67.6 µg m⁻³ at DF, WB and MT sites for women, students and drivers, which were 2.4, 10.3 and 6.4 times the ambient PM_2.5 concentrations, respectively. Elevated PE PM_2.5 levels in the dry season were found at DF (358.8±100.5 µg m⁻³), WB (494.3±15.8 µg m⁻³) and MT (335.1±72.1 µg m⁻³) sites, on average 15 % higher than that at DF and 55 % higher at both WB and MT sites in the wet season. The seasonal variations were attributed to emission sources, meteorological factors and personal activities. In addition, the results show that geological material (35.8 %, 46.0 % and 42.4 %) and organic matter (34.1 %, 23.3 % and 24.9 %) were the major components of PE PM_2.5 at DF, WB and MT sites. It is worth noting that the contribution of heavy metals was higher at WB (1.0 %) than at DF (0.7 %) and MT (0.4 %) sites, strongly influenced by waste burning emission. This results in the highest non-cancer risks of heavy metals to students, 5.1 and 4.8 times the values for women and drivers, respectively. By conducting organic speciation, fingerprints were used to access the exposure and identify the source contributions from typical local anthropogenic sources. The women's exposure concentration to particulate polycyclic aromatic hydrocarbons (PAHs) at DF (77.4±47.9 ng m⁻³) was 1.6 and 2.1 times, respectively, that of students at WB (49.9±30.7 ng m⁻³) and of drivers at MT (37.0±7.4 ng m⁻³). This can be associated with the higher contributions from solid fuels' burning and meat grilling activities to women, resulting in a level 5 times in exceedance of the cancer risk safety threshold ($\mathrm{1}\times {\mathrm{10}}^{-\mathrm{6}}$ ). Phthalate esters (PAEs), commonly used as plasticizers in products, were in high levels in the student exposure PM_2.5 samples (1380.4±335.2 ng m⁻³), owing to obvious waste burning activities nearby. The drivers' exposures to fossil fuel combustion markers of hopanes in PE PM_2.5 at MT (50.9±7.9 ng m⁻³) was 3.0–3.3 times those for women at DF (17.1±6.4 ng m⁻³) and students at WB (15.6±6.1 ng m⁻³). Overall, the current study shows that wood combustion, waste burning, fugitive dust and motor vehicle emissions were the dominant sources of PE PM_2.5 and mainly contributed to its toxicities. The exposure to the heavy metals Pb and Mn caused high non-cancer risks to students at WB, while the severe cancer risk of PAHs was found for women at DF via inhalation. The result of this study provides original data, initial perspective of PM_2.5 personal exposure and health risk assessment in the developing areas. The information encourages the governments to improve the air quality and living standards of residents in this region.

Following population growth and rapid urbanization, West African cities have become major sources of anthropogenic pollution. Additionally, Saharan dust has had a significant impact, representing a potentially toxic mix of sources for the population. This study characterizes the atmospheric composition and its sources in two African capitals, Bamako, Mali and Dakar, Senegal. TSP, PM₁₀ and PM_2.5 samples were collected during the dry season in 2009 when pollution levels were high: chemical analysis included organic carbon (OC), elemental carbon (EC), ions, and metals. PM_2.5 and PM₁₀ concentrations were 5–10 times and 3–8 times higher, respectively, than the 2005 WHO 24 h standards. Using PCA and PMF methodologies, five sources were identified in each city. In Bamako, traffic (motor vehicles and resuspended road dust) was the prevailing source of PM_2.5 and PM₁₀, accounting for 47% and 45%, respectively. Crustal dust was the second most important source (24–30%), followed by solid fuel combustion (16–13%) and secondary aerosols (10–16%). In Dakar, the following sources of PM_2.5 and PM₁₀ are identified: traffic (49%), mineral dust (16–25%), sea salts (15–20%) and industries (10–11%). Our study provides crucial information about the historical change in source characteristics in these two African cities, which can help for future mitigation strategies.

The physico-chemical characteristics of particulate matter (PM) in African cities remain poorly known due to scarcity of observation networks. Magnetic parameters of PM are robust proxies for the emissions of Fe-bearing particles. This study reports the first magnetic investigation of PM2.5 (PM with aerodynamic size below 2.5 μm) in Africa performed on weekly PM2.5 filters collected in Abidjan (Ivory Coast) and Cotonou (Benin) between 2015 and 2017. The magnetic mineralogy is dominated by magnetite-like low coercivity minerals. Mass normalized SIRM are 1.65 × 10⁻² A m² kg⁻¹ and 2.28 × 10⁻² A m² kg⁻¹ for Abidjan and Cotonou respectively. Hard coercivity material (S-ratio = 0.96 and MDF = 33 mT) is observed during the dry dusty season. Wood burning emits less iron oxides by PM2.5 mass when compared to traffic sources. PM2.5 magnetic granulometry has a narrow range regardless of the site or season. The excellent correlation between the site-averaged element carbon concentrations and SIRM suggests that PM2.5 magnetic parameters are linked to primary particulate emission from combustion sources.

Biomass burning (BB) results from complex interactions between ecosystems, humans, and climate, releasing large amounts of gases and particles. Accurate BB emission estimates are essential for air quality, climate studies, and impact assessments. Various existing bottom-up BB emission inventories show significant discrepancies, varying by factors of 2 to 4 due to uncertainties in burned areas (BAs), emission factors (EFs), and vegetation parameters such as biomass density (BD) and burning efficiency (BE). Here, we investigate the role of vegetation parameters in these discrepancies in Africa. Two BB emission inventories, AMMABB-like (African Monsoon Multidisciplinary Analysis Biomass Burning) and GFED-like (Global Fire Emission Database) were developed for Organic Carbon (OC) and Black Carbon (BC). Both inventories used identical fire products, vegetation maps, and EF but different BD and BE values. Results highlight substantial differences in BD and BE, with relative gaps ranging from 44% to 85.12%, explaining the observed differences between BB emission inventories. Key vegetation classes responsible for BB emissions were identified. Discrepancies of 2.4 to 3.9 times were observed between AMMABB-like and GFED4-like, with higher values in the Southern Hemisphere. Better BD and BE estimates with regional distinctions for both hemispheres would improve BB emission accuracy in Africa.

This study aimed to characterise aerosols sampled in the vicinity of a major industrialised area, i.e. the Vaal Triangle. It included thedetermination of oxidative potential as a predictive indicator of particle toxicity. Aerosol samples were collated through the cascadefiltering during an eight-month period (12 h over three days in one week). Three size fractions were analysed for organic carbon(OC), black carbon (BC) and oxidative potential (OP), while ionic content was presented as monthly and seasonal concentrations. Thecontinuous measurement of black carbon by an optical attenuation instrument was collated concurrently with cascade filtering. Thecarbonaceous content was low compared to the ionic one. Within the carbonaceous concentrations, the organic carbon was higherthan concentrations of black carbon in both seasons in the ultra-fine fraction; the opposite was the case for the fine fraction, whilethe coarse fraction concentrations of organic carbon in the dry season had higher concentrations than black carbon in the wet seasonand organic carbon in the wet season. The OP tended to increase as the size was decreasing for wet season aerosols, whereas, forthe dry season, the highest OP was exerted by the fine fraction. The ultrafine fraction was the one showing the most contrasting OPbetween the two seasons. Continuous monitoring indicated that the higher BC concentrations were recorded in the dry/winter partof the year, with the daily pattern of concentrations being typically bimodal, having both the morning and evening peaks in bothseasons. Within the ionic content, the dominance of sulphate, nitrate and ammonium was evident. Multiple linear correlations wereperformed between all determined compounds. Strong correlations of carboxylic acids with other organic compounds were revealed.These acids point to emissions of VOC, both anthropogenic and biogenic. Since they were equally present in both seasons, a mixtureof sources was responsible, both present in the wider area and throughout the year.