Silver-based metal–organic decomposition inks composed of silver salts, complexing agents and volatile solvents are now the subject of much research due to the simplicity and variability of their preparation, their high stability and their relatively low sintering temperature. The use of this type of ink in inkjet printing allows for improved cost-effective and environmentally friendly technology for the production of electrical devices, including flexible electronics. An approach to producing a silver salt-based reactive ink for jet printing has been developed. The test images were printed with an inkjet printer onto polyimide substrates, and two-stage thermal sintering was carried out at temperatures of 60 °C and 100–180 °C. The structure and electrical properties of the obtained conductive lines were investigated. As a result, under optimal conditions an electrically conductive film with low surface resistance of approximately 3 Ω/square can be formed.
14 December 2021 in IEEE Transactions on Plasma Science
The purpose of this work is to study the dielectric charging of polymer fibers with the electron plasma charging effects accompanied by the emergence of waves propagating along the polymer fiber surface. Monitoring of the charge propagation along the single fiber has been performed using dielectric polyhydroxybutyrate (PHB) fibers obtained by the electrospinning (ESP) method under the electron beam inside the scanning electron microscope chamber. The mechanical effect of the electron beam on the polymer fibers has been detected in a time-lapse mode. The influence of the polymer surface irregularities and mechanical defects on the fiber charging has been demonstrated. Plasma mechanism is typical not only for electrophysical phenomena but also for the control of mechanical movement of the fibers by the electron beam and the charge propagation during electron-beam-induced melting and in the presence of hydrodynamic polymer flows. It is assumed that the mechanical effect in the methods using an electron beam (and plasma on the dielectric surface) as an impact source can be determined by the following factors: pressure of the electron beam and the electric field, contribution of the secondary emission, thermal/thermomechanical factors, and dynamic balance or competition between all the forces affecting the sample (electron-beam pressure, gravity pressure, recoil pressure during evaporation, vapor pressure/surface tension, and so on). In addition to purely scientific interest, the above phenomena are also of significant applied interest since the influence of the polymer fiber charging on the separation procedure of aerosols in nonwoven filters is well known, and hence, charging of such polymer fibers is important for some energy storage devices.
1 March 2019 in Russian Journal of Physical Chemistry B
An oxovanadium(IV) complex with dimethyl sulfoxide exhibits a substantial catalytic activity for the reaction of polymerization of 2-hydroxyethyl methacrylate (HEMA) with high selectivity for...
The effects of mono- and disubstituted phosphates on the photolysis reaction of reduced nicotinamide adenine dinucleotide (NADH) in a frozen (77 K) aqueous solution were studied by EPR. The dependence of the yield of the paramagnetic intermediates of the reaction, that is, the NADH+ cation radical and atomic hydrogen, on the concentration of phosphates was determined. The results were interpreted from the point of view of the basicity and electron acceptor properties of phosphates. Electron spectroscopy data revealed a significant acceleration of auto-oxidation and photoinduced oxidation of NADH under normal conditions (20°C, aqueous medium, phosphate buffer, pH 6.3). The rate of the dark reaction was directly proportional to the total concentration of orthophosphates and hydrophosphates and was insensitive to oxygen. On the basis of experiments with a nitroxyl trap, the conclusion was made that the reaction is not of a radical nature.