Hydrate-based CO₂ sequestration is a novel approach that can not only realize permanent CO₂ sequestration but can also form an artificial cap to prevent its upward migration. In this work, a self-developed large-scale 3D apparatus was employed to investigate hydrate formation characteristics in hydrate-based CO₂ sequestration at a constant liquid CO₂ injection rate through a vertical well for the first time. Temperature and pressure evolutions in the sediment were analyzed in detail. Key indicators, including cumulative sequestered CO₂, CO₂ in hydrate and liquid phases, the instantaneous hydrate conversion, and liquid CO₂ retention rates, were calculated. The results show that hydrate continuously forms with increased CO₂ injection and exhibits strong heterogeneity due to the variation in hydrate formation rate and quantity. Severe liquid CO₂ heterogeneous figuring phenomena occur since hydrate deteriorates the effective pore structure and topology, resulting in relatively small cumulative sequestered CO₂ when a large amount of CO₂ is released from the outlet. Meanwhile, the instantaneous hydrate conversion and liquid CO₂ retention rates have large fluctuations owing to water consumption and variation in the effective contact area between liquid CO₂ and water. However, hydrate formation does not cause blockage of wellbore and formation nearby under given experimental conditions, which is beneficial for hydrate formation in deeper sediment. This study provides insights into hydrate formation and liquid CO₂ immigration regularity during hydrate-based CO₂ sequestration and demonstrates its feasibility at a field scale.

In the longstanding development of hydrate-bearing sediment (HBS) reservoirs, slow and permanent deformation of the formation will occur under the influence of stress, which endangers the safety of hydrate development projects. This paper takes hydrate-bearing sandy sediment (HBSS) as the research object and conducts triaxial compression creep tests at different saturation degrees (20%, 30%, and 40%). The results show that the hydrate-containing sandy sediments have strong creep characteristics, and accelerated creep phenomenon will occur under the long-term action of high stress. The longstanding destructive power of the specimen progressively raises with the increase in hydrate saturation, but the difference in the triaxial strength of the specimen progressively increases. This indicates that the damage to the hydrate structure during long-term loading is the main factor causing the strength decrease. Further, a new nonlinear creep constitutive model was developed by using the nonlinear Burgers model in series with the fractional-order viscoplastic body model, which can well describe the creep properties of HBSS at different saturation levels.

During drilling operations, drilling fluids undergo heat exchange with hydrate-bearing formations. The intrusion of drilling fluids affects hydrate stability, leading to variations in stress fields around a wellbore and complex scenarios such as borehole collapse, significantly hindering the efficient development of natural gas hydrate resources. This study establishes a thermo-hydro-mech model for hydrate-bearing inclined wells based on linear thermoelastic porous media theory and an appropriately high inhibitive drilling fluid temperature. This research reveals that drilling should follow directions of minimum horizontal stress or perpendicular to maximum horizontal stress during drilling operations to control wellbore stability. Hydrate decomposition due to factors like drilling fluid pressure and temperature can rapidly reduce the strength of low-saturation formations, significantly increasing the risk of wellbore instability. Therefore, selecting appropriate highly inhibitive and low-temperature drilling fluids during drilling operations helps control hydrate decomposition and reduce fluid intrusion, thereby mitigating risks associated with wellbore instability.

When acoustic waves propagate through hydrate samples, they carry extensive information related to their physical and mechanical properties. These details are comprehensively reflected in acoustic parameters such as velocity, attenuation coefficient, waveform, frequency, spectrum, and amplitude variations. Based on these parameters, it is possible to invert the physical and mechanical indicators and microstructural characteristics of hydrate samples, thereby addressing a series of issues in hydrate development engineering. This study first provides an overview of the current applications and prospects of acoustic testing in hydrate development. Subsequently, it systematically elaborates on the progress in research on acoustic testing systems for hydrate samples, including the principles of acoustic testing, ship-borne hydrate core acoustic detection systems, laboratory hydrate sample acoustic testing systems, and resonance column experimental systems. Based on this foundation, this study further discusses the development trends and challenges of acoustic testing equipment for hydrate-bearing sediments.