Addressing the issues of low permeability, stress sensitivity in CBM reservoirs, and severe reservoir damage from traditional fracturing fluids, we prepared a Gemini surfactant (designated GEM-CBM) for CBM development using ethanolamine, epichlorohydrin, and alkylamidopropyl dimethylamine as feedstocks. On this basis, we further developed a clean fracturing fluid system. The synthesis process of GEM-CBM was optimized via single-factor and orthogonal experiments. The surface activity of GEM-CBM was assessed through surface tension measurements, whereas the sand-carrying capacity, the rheological properties, gel-breaking performance, and reservoir compatibility were comprehensively examined. The optimal conditions for GEM-CBM are listed as follows: the molar ratio of intermediate to alkylamidopropyl dimethylamine being 1:2.2, reacted at 80 °C for 20 h, with a conversion rate of 96.5%. FTIR verified the existence of characteristic functional groups, and EA results matched the theoretical molecular composition. GEM-CBM has good performance, with a critical micelle concentration (CMC) of 19.0 μmol/L and a surface tension at CMC (γCMC) of 37.44 mN/m. The optimized clean fracturing fluid (formulation: 2.3% GEM-CBM + 0.3% Tween-80 + simulated formation water with 150,000 mg/L mineralization) exhibited a viscosity of 82 mPa·s (66.7% viscosity retention rate) after being subjected to 100 min of shearing at 90 °C and 170 s⁻¹. At 90 °C, the proppant settlement velocity was less than 0.15 mm/s, and complete gel breaking was achieved within 30 min without residues. For coal cores from the Qinshui Basin, the permeability recovery rate reached 78.6%. The permeability recovery rate of coal cores from the Qinshui Basin reached 78.6%. This fracturing fluid realizes viscosity enhancement and sand carrying via the worm-like micellar network formed by GEM-CBM, inducing minimal damage to CBM reservoirs and offering technical support for efficient CBM extraction.

This paper proposed a fracture propagation model of water-based fracturing based on seepage–stress–damage coupling, which was employed to analyse the effects of different water-based fracturing fluid properties and rock parameters on the propagation behaviour of reservoir fractures in low-permeability reservoirs. Concurrently, molecular dynamics theory and mechanical analysis of reservoir fractures were employed to elucidate the microscopic mechanism of water-based fracturing on fracture propagation. The results showed that the apparent viscosity of water-based fracturing fluid primarily contributed to elevated fracture internal pressures through the seepage reduction in water-based fracturing fluid at the coal fracture surface. A substantial impact on the minimum fracturing pressure of coal fractures that rapidly pierce the coal rock and an increasing crack extension was notably presented by the low filtration and high viscosity of water-based fracturing fluids. Furthermore, the reservoir pressure and the crack turning angle were not conducive to the effective expansion of coal seam fractures, whereas the reservoir temperature exhibited a positive proportional relationship with deep coal seam fractures.

A metal-doped modified CO oxidation catalyst with strong adsorption and water resistance for coalbed methane was prepared by the CO precipitation method. The CO ablation characteristics were tested, and the Cu Mn catalyst synthesized by metal Ce doping achieved an instantaneous ablation efficiency of 80% when in contact with CO at room temperature. By analyzing the surface crystal structure and pore characteristics, as well as by testing the ablation properties, it was found that the CO oxidation catalyst synthesized by Ce had the best effect at a precipitation temperature of 70 °C. A water-resistant CO oxidation catalyst was synthesized by adding polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP). After storage at a relative humidity of 90%, it still had a CO adsorption rate of about 85%. The water-resistant CO oxidation catalyst prepared with polyvinyl alcohol (PVA) as an additive had a higher content of CeO₂ crystal nuclei, and the PVA-added CO oxidation catalyst had the best ablation characteristics. In the evaluation of the water-resistant steam ablation process, the CuMnO_x-Ce-PVA catalyst showed a significant increase in intermediate products during the stress process under water vapor conditions and a decrease in the peak value of the catalyst’s binding to water, and the catalyst has a particular inhibitory influence on the adsorption of water molecules on its surface. Due to its outstanding water resistance, the catalyst was able to retain good ablation characteristics.

Pre-extraction gas technology is commonly used in coal mines to extract gas from single coal seams, initial protective layers, and both unprotected and protected coal seams. With the development of drilling equipment, directional long drilling, pre-extraction, coal seam gas technology has been widely applied, and negative pressure extraction is one of the key factors affecting the effectiveness of directional long drilling gas extraction. In order to determine the reasonable length of directional long boreholes, studying the negative pressure distribution and time-varying rules within such boreholes is of great significance for guiding later borehole layout and gas extraction. The COMSOL Multiphysics software v.5.3. was used to couple and solve the dynamic model of temperature, stress, and seepage in coal-containing gas, as well as the mathematical model of negative pressure attenuation in directional long boreholes. The gas pressure distribution in the coal surrounding the directional long borehole and the distribution and time-varying law of negative pressure in the borehole were studied. Then, the distribution and time-varying law of negative pressure in directional long borehole extraction were tested on site. Research has shown that the negative pressure attenuation during directional long drilling has a relatively small impact on the effectiveness of coal gas extraction, while the negative pressure at the hole opening is the key factor affecting the effectiveness of gas extraction. In the early stage of extraction, as the drilling depth increases, the pressure loss inside the hole increases and the negative pressure inside the hole decreases. As the extraction time becomes longer, the pressure loss inside the borehole decreases and the negative pressure inside the borehole gradually returns to the negative pressure value at the orifice. The gas flow velocity inside the extraction borehole gradually increases from the bottom of the hole to the hole opening, and the flow velocity at the bottom of the hole remains basically constant. The gas flow velocity inside the hole gradually decreases with the extension of extraction time, and the smaller the distance from the extraction hole opening, the greater the flow attenuation. The collapse of drilling holes during extraction affects the attenuation of negative pressure inside the hole in the short term. As the extraction time increases, the impact of the collapse on the negative pressure inside the hole is limited. The temperature of coal can significantly affect the negative pressure and gas flow distribution inside the pores. Considering the temperature effect, the gas flow velocity inside the pores is higher and the pressure loss is lower in the short term. On-site tests have determined that the depth of ultra-long directional drilling holes is shallower than 327 m, and the negative pressure changes inside the borehole are not significantly different from the negative pressure at the hole opening. The negative pressure stabilization speed near the hole opening and bottom is fast, usually reaching its peak within 3–10 min. The negative pressure stabilization process from the borehole opening to the hole bottom shows a “fast slow fast” trend. When using double-sided extraction, the time for negative pressure to reach stability is significantly shortened compared to single-sided extraction, and double-sided extraction is beneficial for improving the effectiveness of coalbed methane extraction.

To enhance the permeability of coal seam and improve the gas extraction efficiency is an effective measure to ensure the safety of coal mine production, especially, the research of hydraulic fracturing technology has shown better permeability enhancement efficiency of coal seam. However, when the technology is faced with deep and high stress environment, it is easy to cause“Water lock” in the area near the borehole, thus seriously hindering the efficiency of gas extraction. In order to solve the above problems, we deepened the study of more suitable for the upper hole fracturing resistance, hanging sand, anti-swelling, environmental protection and other requirements of cracking fluid: X₃ thickening agent + P₁ anti-expansion agent + J₃ glue breaking agent, etc., and determined the matching S1 fracturing sand,In Songzao Coal Mine, the gas extraction effect is good after sand fracturing, and the average pure amount of gas extraction is 0.0036 m³/min, which is more than 2 times compared with water fracturing hole. The concentration of gas extraction is up to 65%, and it is 26% on average, which is more than 1 times compared with the concentration of water fracturing hole.The results provide parameter support for improving seam permeability and gas production efficiency, and provide important guidance for mine safety production.