Triple superphosphates [TSPs, Ca(H₂PO₄)₂·H₂O] were produced by exothermic reactions of oyster shells and different concentrations of phosphoric acid (10, 20, 30, 40, 50, 60, and 70% w/w) in a molar ratio of 1:2. The percentage yields, P₂O₅ and CaO contents, metal impurities, and thermal behaviors of all the as-prepared products are dependent on the concentrations of phosphoric acid added during the production processes, which confirm to get the best optimum of 60% w/w phosphoric acid. All the as-prepared products were characterized by several characterization methods [X-ray fluorescence, thermal gravimetric/derivative thermal gravimetric analysis, powder X-ray diffraction, Fourier-transform infrared spectroscopy, and scanning electron microscopy], verifying that all the obtained compounds are TSP that can be used as fertilizers without metal toxic contaminants. From the successful results, the method for TSP production can be applied in the fertilizer industry based on starting waste materials of oyster shells that can replace the use of unsustainable phosphate or calcium minerals obtained from nonliving things.

Waste oyster shells were utilized to produce calcium carbonate (CaCO₃) by grinding. This CaCO₃ was then reacted with acetic acid to yield calcium acetate monohydrate (Ca(CH₃COO)₂·H₂O). Both CaCO₃ and Ca(CH₃COO)₂·H₂O were used as precursors for synthesizing calcium oxide (CaO) through thermal decomposition at 900 °C and 750 °C, respectively. The yields of CaO from both precursors, determined through calcination experiments and thermogravimetric analysis (TGA), exceeded 100% due to the high purity of the raw agents and the formation of calcium hydroxide (Ca(OH)₂). X-ray fluorescence (XRF) analysis revealed a CaO content of 87.8% for CaO-CC and 91.5% for CaO-CA, indicating the purity and contamination levels. X-ray diffraction (XRD) patterns confirmed the presence of CaO and minor peaks of Ca(OH)₂, attributed to moisture adsorption. Fourier-transform infrared (FTIR) spectroscopy identified the vibrational characteristics of the Ca-O bond. Scanning electron microscopy (SEM) showed similar morphologies for both CaO-CC and CaO-CA, with CaO-CA displaying a significant amount of rod-like crystals. Based on these results, calcium acetate monohydrate (CA) is recommended as the superior precursor for synthesizing high-purity CaO, offering advantages for various applications.

The search for sustainable resources remains a subject of global interest and the conversion of the abundantly available bivalve shell wastes to advanced materials is an intriguing method. By grinding, calcium carbonate (CaCO₃) powder was obtained from each shell of bivalves (cockle, mussel, and oyster) as revealed by FTIR and XRD results. Each individual shell powder was reacted with H₃PO₄ and H₂O to prepare Ca(H₂PO₄)₂·H₂O giving an anorthic crystal structure. The calcination of the mixture of each shell powder and its produced Ca(H₂PO₄)₂·H₂O, at 900 °C for 3 h, resulted in rhombohedral crystal β-Ca₃(PO₄)₂ powder. The FTIR and XRD data of the CaCO₃, Ca(H₂PO₄)₂·H₂O, and Ca₃(PO₄)₂ prepared from each shell powder are quite similar, showing no impurities. The thermal behaviors of CaCO₃ and Ca(H₂PO₄)₂·H₂O produced from each shell were slightly different. However, particle sizes and morphologies of the same products obtained from different shells were slightly different—but those are significantly different for the kind of the obtained products. Overall, the products (CaCO₃, Ca(H₂PO₄)₂·H₂O, and Ca₃(PO₄)₂) were obtained from the bivalve shell wastes by a rapidly simple, environmentally benign, and low-cost approach, which shows huge potential in many industries providing both economic and ecological benefits.

This work presents the efficient, green, and low-cost preparation of calcium lactate by using bivalve-shell wastes (cockle, mussel, and oyster shells) as raw materials. Three bivalve shells, a cockle, mussel, and oyster, were used separately as an alternative calcium-source material for the preparation of calcium lactate. The bivalve-shell waste was cleaned and milled, obtaining calcium carbonate (CaCO₃) powder, which reacted to the lactic acid, forming calcium lactate. The effects of different calcium sources (cockle, mussel, and oyster) and different lactic acid concentrations (6, 8, and 10 mol/L) on the physicochemical properties of the synthesized calcium lactates were then investigated. The results pointed out that the highest solubility of the product was observed when 6 mol/L lactic acid and cockle-shell derived CaCO₃ were employed for the calcium lactate preparation. The thermal decompositions of all calcium lactates occurred in three processes: dehydration, ethyl-lactate elimination, and decarbonization, respectively. The results, obtained from an infrared spectrometer, X-ray diffractometer, thermogravimetric analyzer, and scanning electron microscope, confirmed the formation of calcium lactate pentahydrate (Ca(CH₃CHOHCOO)₂·5H₂O). The diffractograms also indicated the presence of two enantiomers of Ca(CH₃CHOHCOO)₂·5H₂O, namely, of dl- and l-enantiomers, which depended on the lactic acid concentration used in the preparation process. The morphologies of calcium lactates show the firewood-like crystals in different microsizes, together with smaller irregular crystals. In summary, this work reports an effective process to prepare the valuable calcium lactates by using the cheap bivalve-shell-derived CaCO₃ as a renewable calcium source.

Calcium dihydrogen phosphate monohydrate (Ca(H₂PO₄)₂·H₂O) (a fertilizer) was successfully synthesized through a recrystallization process using prepared triple superphosphate (TSP) derived from oyster shell waste as the starting material. This bio-green, eco-friendly process to produce an important fertilizer can promote a sustainable society. The shell-waste-derived TSP was dissolved in distilled water and kept at 30, 50, and 80 °C. Non-soluble powder and TSP solution were obtained. The TSP solution fractions were then dried, and the recrystallized products (RCP30, RCP50, and RCP80) were obtained and confirmed as Ca(H₂PO₄)₂·H₂O. Conversely, the non-soluble products (NSP30, NSP50, and NSP80) were observed as calcium hydrogen phosphate dihydrate (CaHPO₄·2H₂O). The recrystallized yields of RCP30, RCP50, and RCP80 were found to be 51.0%, 49.6%, and 46.3%, whereas the soluble percentages were 98.72%, 99.16%, and 96.63%, respectively. RCP30 shows different morphological plate sizes, while RCP50 and RCP80 present the coagulate crystal plates. X-ray diffractograms confirmed the formation of both the NSP and RCP. The infrared adsorption spectra confirmed the vibrational characteristics of HPO₄²⁻, H₂PO₄⁻, and H₂O existed in CaHPO₄·2H₂O and Ca(H₂PO₄)₂·H₂O. Three thermal dehydration steps of Ca(H₂PO₄)₂·H₂O (physisorbed water, polycondensation, and re-polycondensation) were observed. Ca(H₂PO₄)₂ and CaH₂P₂O₇ are the thermodecomposed products from the first and second steps, whereas the final product is CaP₂O₆.

This work aimed to synthesize and characterize the calcium acetate monohydrate (Ca(CH₃COO)₂·H₂O) from the exothermic reaction between CaCO₃ powder derived from cockle shells with three different acetic acids (8, 10, and 12 mol L^-1) concentrations by the rapid and easy process without pH and temperature control to lead to cheap chemical production. The physicochemical characteristics of all synthesized Ca(CH₃COO)₂·H₂O samples are investigated based on the chemical compositions, crystal structures, vibrational characteristics, morphologies, and thermal behavior to confirm the target compound. A suitable concentration of 10 mol L^-1 CH₃COOH was chosen to produce Ca(CH₃COO)₂·H₂O with the highest yield (96.30 %), maximum calcium content (96.2 % CaO) with lower impurities, and time consumption of 17 h. The calcium acetate product obtained from cockle shells in this work shows differences in thermal stability, morphological structure purity, %yield, and metal contamination with those reported obtained from other sources and another shell type in the previous work. This research investigates the transformation of cockle shell waste into CaCO₃ for the production of calcium acetate, aiming to address environmental sustainability concerns by reducing the use of calcium ore resources and greenhouse gas emissions.