The aluminum electrolysis industry continually and unavoidably produces hazardous solid waste in the form of carbon anode slag. Carbon anode slag poses a serious environmental pollution risk, and it must be disposed of in a harmless manner. On the other hand, it contains a few valuable resources, as well. In order for the aluminum electrolysis industry to develop in an environmentally friendly and high-quality manner, the harmless disposal of carbon anode slag and its resourceful utilization are of considerable importance. The selective comminution of carbon and cryolite particles in carbon anode slag can be effectively achieved with grinding pretreatment. However, the optimization study of grinding process parameters has yet to be investigated. Therefore, firstly, the mineralogical characteristics and existing mode of carbon anode slag from the perspective of mineralogical properties are analyzed in this study. Then, the effects of grinding time, grinding concentration, and steel ball diameter on the particle size of the ground product (γ_{−0.074 mm}) are investigated using response surface analysis. The results showed that the effect of grinding time was the most significant, followed by grinding concentration and steel ball diameter. In addition, the performance of the multi-stage flotation process for separating the −0.074 mm ground product was analyzed. Cryolite with a purity of 93.12% and a carbon product with an ash content of 10.67% could be simultaneously obtained through multi-stage flotation. It should be pointed out that the deep dissociation and efficient recovery of fine undissociated particles still need to be further explored.

The separation of fine coal has been widely discussed in the coal preparation industry due to its high economic potential. Dense medium cyclone (DMC) is the most efficient equipment available for fine coal separation. However, the industrial application of DMC is far from satisfactory due to operational difficulties and maintenance. In this research, particle settling behavior in a dense medium cyclone was analyzed for improved separation. The calculation result about feed pressure and separation lower limit, which fits the experimental data well, might be a guidance for industrial DMC design and operation. According to the calculation result, it is highly recommended that the separation lower limit be set at 0.2 mm rather than 0.1 mm, because the feed pressure head required for the latter (50 D) is three times higher than the former (15 D).

Fluorine appears in coal and is released into the atmosphere upon combustion, resulting in harmful impacts on the environment and life, which needs to be removed from coal before utilization. Coal can be processed by flotation and gravity separation to reduce its fluorine content. In this study, a lignite sample from a mine in Shaanxi Province, China, was characterized using the float–sink test, sieving test, X-ray diffraction (XRD), and polarized light microscopy. Mineralogical analysis indicated that the fluorine in coal is mainly contained in Muscovite and polylithionite, and partly in pyrite. The washability and floatability analyses were employed to evaluate the extent of fluorine removal from >0.5 and <0.5 mm size fractions of lignite, respectively. Compared to the raw sample that contained 347.74 μg/g fluorine content, the proposed combination of gravity-flotation separation process decreased the fluorine content to 90.14 μg/g, which meets the requisites of coal standards.