Master equations govern the time evolution of a quantum system interacting with an environment, and may be written in a variety of forms. Time-independent or memoryless master equations, in particular, can be cast in the well-known Lindblad form. Any time-local master equation, Markovian or non-Markovian, may in fact also be written in a Lindblad-like form. A diagonalization procedure results in a unique, and in this sense canonical, representation of the equation, which may be used to fully characterize the non-Markovianity of the time evolution. Recently, several different measures of non-Markovianity have been presented which reflect, to varying degrees, the appearance of negative decoherence rates in the Lindblad-like form of the master equation. We therefore propose using the negative decoherence rates themselves, as they appear in the canonical form of the master equation, to completely characterize non-Markovianity. The advantages of this are especially apparent when more than one decoherence channel is present. We show that a measure proposed by Rivas et al. [Phys. Rev. Lett. 105, 050403 (2010)] is a surprisingly simple function of the canonical decoherence rates, and give an example of a master equation that is non-Markovian for all times $t>0$, but to which nearly all proposed measures are blind. We also give necessary and sufficient conditions for trace distance and volume measures to witness non-Markovianity, in terms of the Bloch damping matrix.

For any master equation which is local in time, whether Markovian, non-Markovian, of Lindblad form or not, a general procedure is given for constructing the corresponding linear map from the initial state to the state at time t, including its Kraus-type representations. Formally, this is equivalent to solving the master equation. For an N-dimensional Hilbert space it requires (i) solving a first order N ²×N ² matrix time evolution (to obtain the completely positive map), and (ii) diagonalizing a related N ²×N ² matrix (to obtain a Kraus-type representation). Conversely, for a given time-dependent linear map, a necessary and sufficient condition is given for the existence of a corresponding master equation, where the (not necessarily unique) form of this equation is explicitly determined. It is shown that a “best possible” master equation may always be defined, for approximating the evolution in the case that no exact master equation exists. Examples involving qubits are given.

The prevailing description for dissipative quantum dynamics is given by the Lindblad form of a Markovian master equation, used under the assumption that memory effects are negligible. However, in certain physical situations, the master equation is essentially of a non-Markovian nature. In this paper we examine master equations that possess a memory kernel, leading to a replacement of white noise by colored noise. The conditions under which this leads to a completely positive, trace-preserving map are discussed for an exponential memory kernel.

The dynamical convergence of a system to the thermal distribution, or Gibbs state, is a standard assumption across all of the physical sciences. The Gibbs state is determined just by temperature and energies of the system. However, at decreasing system sizes, i.e., for nanoscale and quantum systems, the interaction with their environments is not negligible. The question then arises: Is the system's steady state still the Gibbs state? If not, how may the steady state depend on the interaction details? Here, we provide an overview of recent progress on answering these questions. We expand on the state of the art along two general avenues: First, we take the static point-of-view, which postulates the so-called mean force Gibbs state. This view is commonly adopted in the field of strong coupling thermodynamics, where modified laws of thermodynamics and nonequilibrium fluctuation relations are established on the basis of this modified state. Second, we take the dynamical point of view, originating from the field of open quantum systems, which examines the time-asymptotic steady state within two paradigms. We describe the mathematical paradigm, which proves return to equilibrium, i.e., convergence to the mean force Gibbs state, and then discuss a number of microscopic physical methods, particularly master equations. We conclude with a summary of established links between statics and equilibration dynamics and provide an extensive list of open problems. This comprehensive overview will be of interest to researchers in the wider fields of quantum thermodynamics, open quantum systems, mesoscopic physics, statistical physics, and quantum optics and will find applications whenever energy is exchanged on the nanoscale, from quantum chemistry and biology to magnetism and nanoscale heat management.

The Gibbs state is widely taken to be the equilibrium state of a system in contact with an environment at temperature $T$. However, non-negligible interactions between system and environment can give rise to an altered state. Here, we derive general expressions for this mean force Gibbs state, valid for any system that interacts with a bosonic reservoir. First, we derive the state in the weak coupling limit and find that, in general, it maintains coherences with respect to the bare system Hamiltonian. Second, we develop a new expansion method suited to investigate the ultrastrong coupling regime. This allows us to derive the explicit form for the mean force Gibbs state, and we find that it becomes diagonal in the basis set by the system-reservoir interaction instead of the system Hamiltonian. Several examples are discussed including a single qubit, a three-level $V$-system, and two coupled qubits all interacting with bosonic reservoirs. The results shed light on the presence of coherences in the strong coupling regime, and provide key tools for nanoscale thermodynamics investigations.

We consider two recently proposed measures of non-Markovianity applied to a particular quantum process describing the dynamics of a driven qubit in a structured reservoir. The motivation for this study is twofold: on one hand, we study the differences and analogies of the non-Markovianity measures, and on the other hand, we investigate the effect of the driving force on the dissipative dynamics of the qubit. In particular we ask if the driving force introduces new channels for energy and/or information transfer between the system and the environment or if it amplifies existing ones. We show under which conditions the presence of the driving force slows down the inevitable loss of quantum properties of the qubit.