Bruce Sithole

Dr. Bruce Sithole


Research Focus & Metrics

Academic Career Length

37Years (1990-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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15 March 2023 in Sustainability
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Journal Article
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KKKatleho Keneuwe Khoaele
Katleho Keneuwe Khoaele
Oluwatoyin Joseph GbadeyanOluwatoyin Joseph Gbadeyan
Oluwatoyin Joseph Gbadeyan
VCViren Chunilall
Viren Chunilall
BSBruce Sithole
Bruce Sithole
The devastating effect of plastic waste on the ecosystem due to the rapid increase in population has been a concern. Although stakeholders and governments invested in efforts to mitigate plastic waste, their exertions have limited to no effects as the demand for plastic increases annually. Emerging practical advancements in recycling plastic have been critical for achieving a sustainable circular economy. This study reviews the adverse effect of plastic waste on the environment and the inhabiting creature, the regulation for managing plastic waste, and their limitations. This scoping review also provides information on the current route for reducing plastic waste by defining its sources and their applications. After identifying the generation of plastic waste, the plastic polymers are categorized according to the hazard ranking of their monomers according to their environmental toxicity, damaging the inhabiting creature. The discharge pathways of plastic waste into the environment and aquatic systems leading to white pollution and climate change were also determined. Conversion of plastic waste through the remedial channel by manufacturing value-added products using techniques such as reusing, recycling, and energy recovery, reducing the disposal of plastic waste in landfills is outlined. The information on remedial processes provided in this study will help reduce plastic waste from the environment. In addition, correctly applying these suggestions may help reduce environmental pollution and the death of inhabiting creations. Further research is necessary to convert plastic waste as raw materials into high-value products to achieve a circular economy.

13 November 2021 in Cellulose
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Journal Article
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TJThabisile Jele
Thabisile Jele
PLPrabashni Lekha
Prabashni Lekha
BSBruce Sithole
Bruce Sithole

24 May 2024 in Polymers
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Journal Article
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RBRivalani Baloyi Baloyi
Rivalani Baloyi Baloyi
BSBruce Sithole
Bruce Sithole
VCViren Chunilall
Viren Chunilall
The utilisation of cotton waste as precursors in the synthesis of nanocrystalline cellulose has gained significant attention. This approach suggests a sustainable solution to address the growing concern of textile waste accumulation while simultaneously producing a valuable material. The main aim of this study is to examine the properties of cellulose nanocrystals (CNCs) obtained from postconsumer polyester–cotton waste and assess the effect of different fabric structures on the extraction and these properties. To acquire nanocellulose, a thorough decolourisation pretreatment process was utilised, which involved the treatment of polyester–cotton waste with sodium dithionite and hydrogen peroxide. Consequently, the postconsumer material was then treated with an acid hydrolysis method employing a 64% (v/v) sulphuric acid solution at 50 °C for 75 min, resulting in the formation of CNCs with average yield percentages ranging from 38.1% to 69.9%. Separation of the acid from the CNC was facilitated by a centrifugation process followed by dialysis against deionised water. Uniform dispersion was then achieved using ultrasonication. A variety of analytical techniques were employed to investigate the morphological, chemical, thermal, and physical properties of the isolated CNCs. Among these techniques, attenuated total reflection-Fourier-transform infrared spectroscopy (ATR-FTIR), energy-filtered transmission electron microscopy (EF-TEM), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) were utilised to analyse the CNCs. The findings indicated that the separated CNCs exhibited a rod-shaped morphology, measuring between 78 and 358 nm in length and 5 and 16 nm in diameter, and also exhibited high crystallinity (75–89%) and good thermal stability. The extracted CNCs were mixed with polyvinyl alcohol (PVA) and glycerol to assess their reinforcing effect on plastic films. The prepared composite film exhibited improved mechanical properties and thermal stability. Incorporating CNCs led to a 31.9% increase in the tensile strength and a 42.33% rise in the modulus of elasticity. The results from this research proved that CNCs can be extracted from postconsumer mixed fabrics as a potential solution to effectively address the mounting concerns surrounding waste management in the textile industry and also provide avenues for enhancing the qualities of eco-friendly composite films.

Verified
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NSNivisti Singh
Nivisti Singh
BSBruce Sithole
Bruce Sithole
RGRoshini Govinden
Roshini Govinden
Pulp and paper mill sludge (PPMS) is currently disposed of into landfills which are reaching their maximum capacity. Valorisation of PPMS by enzymatic hydrolysis using cellulases is an alternative strategy. Existing commercial cellulases are expensive and contain low titres of β-glucosidases. In this study, β-glucosidase production was optimised by Aspergillus japonicus VIT-SB1 to obtain higher β-glucosidase titres using the One Variable at a Time (OVAT), Plackett Burman (PBD), and Box Behnken design (BBD)of experiments and the efficiency of the optimised cellulase cocktail to hydrolyse cellulose was tested. β-Glucosidase production was enhanced from 0.4 to 10.13 U/mL, representing a 25.3-fold increase in production levels after optimisation. The optimal BBD production conditions were 6 days of fermentation at 20 °C, 125 rpm, 1.75% soy peptone, and 1.25% wheat bran in (pH 6.0) buffer. The optimal pH for β-glucosidase activity in the crude cellulase cocktail was (pH 5.0) at 50 °C. Optimal cellulose hydrolysis using the crude cellulase cocktail occurred at longer incubation times, and higher substrate loads and enzyme doses. Cellulose hydrolysis with the A. japonicus VIT-SB1 cellulase cocktail and commercial cellulase cocktails resulted in glucose yields of 15.12 and 12.33 µmol/mL glucose, respectively. Supplementation of the commercial cellulase cocktail with 0.25 U/mg of β-glucosidase resulted in a 19.8% increase in glucose yield.

23 October 2021 in Biomass Conversion and Biorefinery
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OFOlajumoke D. Fagbemi
Olajumoke D. Fagbemi
JAJerome E. Andrew
Jerome E. Andrew
BSBruce Sithole
Bruce Sithole

1 January 2021 in Current Research in Green and Sustainable Chemistry
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Journal Article
Open access
OFOlajumoke D. Fagbemi
Olajumoke D. Fagbemi
BSBruce Sithole
Bruce Sithole