Improving the long-term stability of perovskite solar cells is critical to the deployment of this technology. Despite the great emphasis laid on stability-related investigations, publications lack consistency in experimental procedures and parameters reported. It is therefore challenging to reproduce and compare results and thereby develop a deep understanding of degradation mechanisms. Here, we report a consensus between researchers in the field on procedures for testing perovskite solar cell stability, which are based on the International Summit on Organic Photovoltaic Stability (ISOS) protocols. We propose additional procedures to account for properties specific to PSCs such as ion redistribution under electric fields, reversible degradation and to distinguish ambient-induced degradation from other stress factors. These protocols are not intended as a replacement of the existing qualification standards, but rather they aim to unify the stability assessment and to understand failure modes. Finally, we identify key procedural information which we suggest reporting in publications to improve reproducibility and enable large data set analysis.
1 May 2011 in Solar Energy Materials and Solar Cells
This work is a brief account of the most recent developments observed in the application of ZnO nanostructured materials in excitonic solar cells (organic, hybrid and dye sensitized solar cells). Special emphasis is made to one-dimensional (1D), vertically-aligned nanostructures (nanowires NW, nanorods NR) of ZnO semiconductor oxide and the extensive research work invested in recent years for its application as an electron acceptor material in solar cells. Our aim is to give the reader a broad overview of this semiconductor oxide and to understand the causes, advantages and disadvantages, for its application in a well-aligned nanostructure form. We briefly describe the most applied methodologies for its synthesis as well as the effect on surface area, electron transport and charge recombination when it is applied as an electron transport material in excitonic solar cells (XSCs). The importance of low-cost and easy-scalable synthesis techniques, as well as stability issues on these solar cells are discussed. Finally, we include a brief analysis of the possible future trends for the application of this interesting semiconductor oxide in XSCs.
3 January 2008 in Journal of the American Chemical Society