A new approach, based on dielectrophoresis (DEP), was developed in this work to enhance traditional adsorption for the removal of ammonia nitrogen (NH₃-N) from wastewater. The factors that affected the removal efficiency were systematically investigated, which allowed us to determine optimal operation parameters. With this new method we found that the removal efficiency was significantly improved from 66.7% by adsorption only to 95% by adsorption-DEP using titanium metal mesh as electrodes of the DEP and zeolite as the absorbent material. In addition, the dosage of the absorbent/zeolite and the processing time needed for the removal were greatly reduced after the introduction of DEP into the process. In addition, a very low discharge concentration (C, 1.5 mg/L) of NH₃-N was achieved by the new method, which well met the discharge criterion of C < 8 mg/L (the emission standard of pollutants for rare earth industry in China).

In the present study, PbO₂ electrodes, doped with different doses of Er (0%, 0.5%, 1%, 2%, and 4%), were fabricated and characterized. Surface morphology characterization by SEM-EDS and XRD showed that Er was successfully doped into the PbO₂ catalyst layer and the particle size of Er-PbO₂ was reduced significantly. Electrochemical oxidation of sulfamerazine (SMR) in the Er-PbO₂ anode system obeyed te pseudo first-order kinetic model with the order of 2% Er-PbO₂ > 4% Er-PbO₂ > 1% Er-PbO₂ > 0.5% Er-PbO₂ > 0% PbO₂. For 2% Er-PbO₂, k_SMR was 1.39 h⁻¹, which was only 0.93 h⁻¹ for 0% PbO₂. Effects of different operational parameters on SMR degradation in 2% Er-PbO₂ anode system were investigated, including the initial pH of the electrolyte and current density. Under the situation of an initial pH of 3, a current density of 30 mA·cm⁻², a concentration of SMR 30 mg L⁻¹, and 0.2 M Na₂SO₄ used as supporting electrolyte, SMR was totally removed in 3 h, and COD mineralization efficiency was achieved 71.3% after 6 h electrolysis. Furthermore, the degradation pathway of SMR was proposed as combining the active sites identification by density functional calculation (DFT) and intermediates detection by LC-MS. Results showed that Er-PbO₂ has great potential for antibiotic wastewater treatment in practical applications.