Lithium-ion battery recycling includes discharging and processing exhausted batteries to recover valuable metals for reuse in new battery production. The improper disposal of e-waste draws attention to the possibility of reprocessing used lithium-ion batteries to make progress in recovering valuable metals. In this study, using biodegradable mixed organic acids, valuable metals were extracted from used batteries by a hydrometallurgical process under optimal conditions such as a stirring speed of 200 rpm, mixed acid concentration of ascorbic acid/citric acid (AA/CA) of 50:50 mM, temperature of 50 °C, time of 50 min, and slurry density of 20 g/L. Kinetic studies verified that the apparent activation energies, 43.6, 70.5, 49.8, 60.6, 45, and 6 kJ/mol, and surface chemical reactions controlled the leaching process for Li, Mn, Co, Ni, and Cu from cathode powder obtained from used LIBs. XRD and FT-IR confirmed the crystalline nature of the cathode powder. UV–visible spectra showed a Co(II) complex with λ_max at 380 nm by reduction of the Co(III) complex. Lithium was recovered by LiF and as MnO₂ using ammonium persulfate. Our efforts aimed to recover it through an economical and environmentally friendly approach.