Leigh Fon Jones

Dr. Leigh Fon Jones

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Research Focus & Metrics

Academic Career Length

25Years (2002-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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17 March 2009 in Dalton Transactions
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Journal Article
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RIRoss Inglis
Ross Inglis
LJLeigh Fon Jones
Leigh Fon Jones
CMConstantinos J. Milios
Constantinos J. Milios
SDSaiti Datta
Saiti Datta
ACAnna Collins
Anna Collins
EBEuan Brechin
Euan Brechin
The synthesis and characterisation of a large family of hexametallic [MnIII 6] Single-Molecule Magnets of general formula [MnIII 6O2(R-sao)6(X)2(sol)4–6] (where R = H, Me, Et; X = −O2CR′ (R′ = H, Me, Ph etc) or Hal−; sol = EtOH, MeOH and/or H2O) are presented. We show how deliberate structural distortions of the [Mn3O] trinuclear moieties within the [Mn6] complexes are used to tune their magnetic properties. These findings highlight a qualitative magneto-structural correlation whereby the type (anti- or ferromagnetic) of each Mn2 pairwise magnetic exchange is dominated by the magnitude of each individual Mn-N-O-Mn torsion angle. The observation of magneto-structural correlations on such large polymetallic complexes is rare and represents one of the largest studies of this kind.

16 May 2007 in Inorganic Chemistry
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Journal Article
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RSRachel Shaw
Rachel Shaw
RLRebecca H. Laye
Rebecca H. Laye
LJLeigh Fon Jones
Leigh Fon Jones
DLDavid M. Low
David M. Low
CTCaytie Talbot-Eeckelaers
Caytie Talbot-Eeckelaers
EMEric J. L. McInnes
Eric J. L. McInnes

13 August 2003 in Angewandte Chemie International Edition
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Journal Article
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DLDavid M. Low
David M. Low
LJLeigh Fon Jones
Leigh Fon Jones
ABAidan Bell
Aidan Bell
EBEuan Brechin
Euan Brechin
TMTalal Mallah
Talal Mallah
EMEric J. L. McInnes
Eric J. L. McInnes

7 October 2004 in Chemistry – A European Journal
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Journal Article
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LJLeigh Fon Jones
Leigh Fon Jones
GRGopalan Rajaraman
Gopalan Rajaraman
JBJonathon Brockman
Jonathon Brockman
MMMuralee Murugesu
Muralee Murugesu
E. Carolina SañudoE. Carolina Sañudo
E. Carolina Sañudo
DCDavid Collison
David Collison

12 November 2002 in Angewandte Chemie International Edition
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Journal Article
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LJLeigh Fon Jones
Leigh Fon Jones
ABAndrei Batsanov
Andrei Batsanov
EBEuan Brechin
Euan Brechin
DCDavid Collison
David Collison
MHMadeleine Helliwell
Madeleine Helliwell
SPStergios Piligkos
Stergios Piligkos

5 September 2011 in Chemical Communications
Verified
Journal Article
Open access
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RIRoss Inglis
Ross Inglis
CMConstantinos J. Milios
Constantinos J. Milios
LJLeigh Fon Jones
Leigh Fon Jones
SPStergios Piligkos
Stergios Piligkos
EBEuan Brechin
Euan Brechin
The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([MnIII 6]) and thirty trinuclear ([MnIII 3]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family members with increasingly puckered configurations, leading to a switch in the pairwise magnetic exchange from antiferromagnetic to ferromagnetic. Examination of both the structural and magnetic data revealed a semi-quantitative magneto-structural correlation, from which the factors governing the magnetic properties could be extracted and used for predicting the properties of new family members and even more complicated structures containing analogous building blocks. Herein we describe an overview of this extensive body of work and discuss its potential impact on similar systems.