A novel sensitive, selective, and reversible cobalt(II) ion optical sensor was prepared by the incorporation of 5-[o-carboxyphenylazo]2,4-dihydroxybenzoic acid [CPDB] and sodium tetraphenylborate (NaTPB) in a plasticized polyvinyl chloride (PVC) membrane containing dioctyl adipate (DOA) as a plasticizer. The influence of several parameters such as pH, base matrix, solvent mediator and reagent concentration was optimized. A comparison of the obtained results with those of previously reported sensors revealed that the proposed method, in addition to being fast and simple, provided a good linear range (0.05–45.20 μM) and low detection limit (0.015 μM). Low detection and quantification limits and excellent selectivity in the presence of interfering ions such as Fe³⁺, Cu²⁺, Ni²⁺, Ag⁺, Au³⁺, Cr³⁺, Cd²⁺, Zn²⁺, Hg²⁺, and SO₄ ²⁻ make it feasible to monitor Co²⁺ ion content accurately and repeatedly in environmental samples with complicated matrices. The optode was regenerated successfully using 0.3 M nitric acid (HNO₃) solution while its response was reversible with a relative standard deviation (RSD) lower than 1.9% for seven replicate determinations of 20 μM Co²⁺ in various membranes. The optode was stable and was stored for at least 15 days without observing any change in its sensitivity.

Growing concerns about the possible toxicity of silver to aquatic organisms, bacteria, and humans have led to newly issued regulations by the United States Environmental Protection Agency (US EPA) and the Food and Drug Administration (FDA) regarding the use of silver. However, the increase in bacterial resistance to antibiotics has led to a resurgence in the use of silver as a biocidal agent in applications ranging from washing machine additives to the drinking water treatment system on the International Space Station (ISS). For Ag⁺ ion detection, a highly sensitive and reversible optical sensor has been established. The optode relies on a novel Schiff base, namely 2-[(benzo[d]thiazol-2-ylimino)methyl]phenol (BTMP) immobilized within PVC film and also incorporated with tris(2-ethylhexyl)phosphate (TEHP) and Aliquat 336 as an ion carrier. Under optimum conditions (i.e. pH 8.5), the proposed sensor displayed a linear response to Ag⁺ over 4.8 × 10⁻⁹ to 1.0 × 10⁻⁵ M (0.8494–1698.7 μg L⁻¹) with limits of detection and quantification of 1.5 × 10⁻⁹ and 4.8 × 10⁻⁹ M (0.2548 and 0.8494 μg L⁻¹), respectively. The sensor's response time was found to be 8.0 min. The sensor was applied successfully to determine Ag⁺ ion in some real samples, including food, biological, water, and environmental samples.

A novel highly selective sensitive optical sensor was prepared via the chemical immobilization of β-2-hydroxybenzyl-5-bromo-2-hydroxyazastyrene (HBBHAS) on an epoxy-activated agarose membrane pieces. The absorbance variation of the immobilized azastyrene film on agarose upon the addition of 1.5 × 10⁻⁵ M aqueous solutions of La³⁺, Y³⁺, Al³⁺, Sc³⁺, Sm³⁺, Eu³⁺, Lu³⁺, Fe³⁺, Ce³⁺, Cr³⁺, S₂O₃ ²⁻, Tb³⁺, Mn²⁺ and KIO₃ revealed substantially higher changes for the Yb³⁺ ion compared to the other considered ions. Thus, using HBBHAS as an appropriate ionophore, a selective optical sensor for Yb³⁺ was prepared via its chemical immobilization on a transparent agarose membrane. The effects of pH, reagent concentration, and time duration of the reaction of immobilizing the reagent were examined. A distinct change in the maximum absorbance of the reagent was established on contact of the sensing membrane with Yb³⁺ ions at pH = 4.25. For the membrane sensor, a linear relationship was observed between the variation in membrane absorbance (ΔA) at 424 nm and Yb³⁺ concentrations in the range of 4.75 × 10⁻⁵ to 6.20 × 10⁻¹⁰ M with a detection limit of 1.9 × 10⁻¹⁰ M for Yb³⁺. The effects of some potentially interfering ions on the assessment of Yb³⁺ were analyzed, and no substantial interference was found. The sensor showed a short response time and decent durability with no reagent leaching. The recovery of Yb³⁺ ions from the sensor material was performed using 0.3 M HNO₃ and its response was reversible and reproducible with RSD ≥ 1.95%. This study reports a non-toxic, economical, stable, accurate, easy-to-use, and novel optical sensor material to assess Yb³⁺ in synthetic and environmental water samples.