Nitrogen removal in the sewage treatment process is a significant challenge. The increase in nitrogen content in sewage leads to the eutrophication of water bodies and the deterioration of water quality in polluted environments. Therefore, converting nitrogen into non-polluting gases is a crucial and essential part of the sewage treatment process. Compared to physical, chemical, and physicochemical methods, biological denitrification is not only simple to operate and economically effective but also has less secondary pollution and saves energy. This paper summarizes the latest research progress on mainstream biological denitrification technology in WWTPS (wastewater treatment plants) and discusses its research background, methodology, and challenges. It is noted that the traditional biological nitrogen removal method is stable and widely used, but it has drawbacks such as high costs and long reaction times, especially in high-nitrogen-load wastewater treatment where its effectiveness is limited. The short-cut nitrification–denitrification process suits high-nitrogen-loading and a low C/N ratio wastewater as it reduces carbon source consumption. However, the problems of water quality fluctuation and unstable dissolved oxygen still need to be solved. The anaerobic ammonia oxidation process efficiently converts ammonia and nitrite to nitrogen using anaerobic ammonia-oxidizing bacteria, consuming less energy but facing limitations due to slow bacterial growth rates and stringent environmental conditions. The heterotrophic nitrification–aerobic denitrification process merges the traits of heterotrophic nitrifying bacteria and aerobic denitrifying bacteria, effectively reducing the ecological footprint and enhancing treatment efficiency. This approach is a pivotal focus for future research endeavors.

Amidst the rapid expansion of the global economy, the demand for energy has escalated. The depletion of traditional energy sources coupled with environmental pollution concerns has catalyzed a shift towards the development and utilization of clean, renewable energy. Biogas, as a renewable energy source, provides diverse applications and holds the potential to alleviate energy shortages. Recently, biogas dry reforming technology has garnered substantial attention as a significant pathway for renewable energy utilization, particularly in the development and optimization of catalysts. Contemporary research predominantly focuses on enhancing the activity and stability of catalysts, with particular emphasis on their resistance to coking and sintering. This review delineates the classification of biogas dry reforming catalysts, their catalytic activity, and issues related to carbon deposition, contrasting biogas dry reforming with traditional dry reforming in catalyst design. It synthesizes numerous studies from recent years aimed at mitigating carbon deposition during the biogas dry reforming process and boosting catalytic activity via active components, carriers, and promoters in both precious and non-precious metal catalysts. Furthermore, it discusses the current challenges of biogas dry reforming technology and outlines prospective future development trends. This discussion provides an in-depth understanding of biogas dry reforming technology and catalyst design, offering insights and recommendations for future research and industrial applications.

Single-atom catalysts (SACs) have attracted extensive attention due to their unique catalytic properties and wide range of applications. Advanced characterization techniques, such as energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscopy, and X-ray absorption fine-structure spectroscopy, have been used to investigate the elemental compositions, structural morphologies, and chemical bonding states of SACs in detail, aiming at unraveling the catalytic mechanism. Meanwhile, theoretical calculations, such as quantum chemical calculations and kinetic simulations, were used to predict the catalytic reaction pathways, active sites, and reaction kinetic behaviors of SACs, providing theoretical guidance for the design and optimization of SACs. This review overviews advanced characterization techniques and theoretical calculations for SACs in Fenton-like chemistry. Moreover, this work highlights the importance of advanced characterization techniques and theoretical calculations in the study of SACs and provides perspectives on the potential applications of SACs in the field of environmental remediation and the challenges of practical engineering.

Developing a green, low-carbon, and circular economic system is the key to achieving carbon neutrality. This study investigated the organics removal efficiency in a three-dimensional electrode reactor (3DER) constructed from repurposed industrial solid waste, i.e., Mn-loaded steel slag, as the catalytic particle electrodes (CPE). The CPE, a micron-grade material consisting primarily of transition metals, including Fe and Mn, exhibited excellent electric conductivity, catalytic ability, and recyclability. High rhodamine B (RhB) removal efficiency in the 3DER was observed through a physical modelling experiment. The optimal operating condition was determined through a single-factor experiment in which 5.0 g·L⁻¹ CPE and 3 mM peroxymonosulfate (PMS) were added to a 200 mL solution of 10 mM RhB under a current intensity of 0.5 A and a 1.5 to 2.0 cm distance between the 2D electrodes. When the initial pH value of the simulated solution was 3 to 9, the RhB removal rate exceeded 96% after 20 min reaction. In addition, the main reactive oxidation species in the 3DER were determined. The results illustrated that HO• and SO4^•− both existed, but that the contribution of SO₄^•− to RhB removal was much lower than that of HO• in the 3DER. In summary, this research provides information on the potential of the 3DER for removing refractory organics from water.