This work deals with the synthesis and characterization of novel Fe-containing sol-gel materials obtained by modifying the composition of a binary SiO₂-CaO parent glass with the addition of Fe₂O₃. The effect of different processing conditions (calcination in air vs. argon flowing) on the formation of magnetic crystalline phases was investigated. The produced materials were analyzed from thermal (hot-stage microscopy, differential thermal analysis, and differential thermal calorimetry) and microstructural (X-ray diffraction) viewpoints to assess both the behavior upon heating and the development of crystalline phases. N₂ adsorption–desorption measurements allowed determining that these materials have high surface area (40–120 m²/g) and mesoporous texture with mesopore size in the range of 18 to 30 nm. It was assessed that the magnetic properties can actually be tailored by controlling the Fe content and the environmental conditions (oxidant vs. inert atmosphere) during calcination. The glasses and glass-ceramics developed in this work show promise for applications in bone tissue healing which require the use of biocompatible magnetic implants able to elicit therapeutic actions, such as hyperthermia for bone cancer treatment.

We present the experimental observation of magnetic field line curvature at the surface of a superconducting film by local quantitative magneto-optics. In addition to the knowledge of the full induction field at the superconductor surface yielding to the quantitative observation of the flux line curvature, our analysis method also allows local value measurements of the electrical current density inside the sample. Thus, we study the interplay between the electrodynamical constraints dictated by the film geometry and the pinning properties of the superconductor. In particular, we investigate the anisotropic vortex pinning, due to columnar defects introduced by heavy ion irradiation, as revealed in the local current density dependence on the vortex curvature during magnetic flux diffusion inside the superconducting film.

Zinc oxide nanoparticles (ZnO NPs) are currently among the most promising nanomaterials for theranostics. However, they suffer from some drawbacks that could prevent their application in nanomedicine as theranostic agents. The doping of ZnO NPs can be effectively exploited to enhance the already-existing ZnO properties and introduce completely new functionalities in the doped material. Herein, we propose a novel synthetic approach for iron-doped ZnO (Fe:ZnO) NPs as a multifunctional theranostic nanoplatform aimed at cancer cell treatment. Pure ZnO and Fe:ZnO NPs, with two different levels of iron doping, were synthesized by a rapid wet-chemical method and analyzed in terms of morphology, crystal structure and chemical composition. Interestingly, Fe:ZnO NPs featured bioimaging potentialities thanks to superior optical properties and novel magnetic responsiveness. Moreover, iron doping provides a way to enhance the electromechanical behavior of the NPs, which are then expected to show enhanced therapeutic functionalities. Finally, the intrinsic therapeutic potentialities of the NPs were tested in terms of cytotoxicity and cellular uptake with both healthy B lymphocytes and cancerous Burkitt’s lymphoma cells. Furthermore, their biocompatibility was tested with a pancreatic ductal adenocarcinoma cell line (BxPC-3), where the novel properties of the proposed iron-doped ZnO NPs can be potentially exploited for theranostics.

We measure current-voltage characteristics as function of magnetic field and temperature in Nb strips of different thickness and width. The instability voltage of the flux-flow state related to the vortex critical velocity v$\ast${} is studied and compared with the Larkin-Ovchinnikov theory. Beside the usual power-law dependence v$\ast${}$\approx${}B$-${}1/2, in the low-field range a new crossover field, Bcr1, is observed below which v$\ast${} decreases by further lowering the external magnetic field B. We ascribe this unexpected crossover to vortex channeling due to a fanlike penetration of the applied magnetic field as confirmed by magneto-optic imaging. The observation of Bcr1 becomes a direct evidence of a general feature in type-II superconducting films at low fields that is a channel-like vortex motion induced by the inhomogeneous magnetic state caused by the relatively strong pinning.

We investigate the neutron damage expected in high-temperature superconducting tapes that will be employed in compact fusion reactors. Monte Carlo simulations yield the expected neutron spectrum and fluence at the magnet position, from which the primary knock-on atom energy distributions can be computed for each atomic species comprising the superconductor. This information is then employed to characterize the displacement cascades, in terms of size and morphology, through molecular dynamics simulations. The expected radiation environment is then compared with the neutron spectrum and fluences achievable at the facilities currently available for experimental investigation in order to highlight similarities and differences that could be relevant to the understanding of the radiation hardness of these materials in real fusion conditions. We find that the different neutron spectra result in different damage regimes, the irradiation temperature influences the number of generated defects, and the interaction of the neutrons with the superconductor results in a local increase in temperature. These observations suggest that further experimental investigations are needed in different regimes and that some neutron shielding will be necessary in compact fusion reactors.