Pulsed Laser Deposition is a commonly used non-equilibrium physical deposition technique for the growth of complex oxide thin films. A wide range of parameters is known to influence the properties of the used samples and thin films, especially the oxygen-vacancy concentration. One parameter has up to this point been neglected due to the challenges of separating its influence from the influence of the impinging species during growth: the UV-radiation of the plasma plume. We here present experiments enabled by a specially designed holder to allow a separation of these two influences. The influence of the UV-irradiation during pulsed laser deposition on the formation of oxygen-vacancies is investigated for the perovskite model material SrTiO3. The carrier concentration of UV-irradiated samples is nearly constant with depth and time. By contrast samples not exposed to the radiation of the plume show a depth dependence and a decrease in concentration over time. We reveal an increase in Ti-vacancy–oxygen-vacancy-complexes for UV irradiated samples, consistent with the different carrier concentrations. We find a UV enhanced oxygen-vacancy incorporation rate as responsible mechanism. We provide a complete picture of another influence parameter to be considered during pulsed laser depositions and unravel the mechanism behind persistent-photo-conductivity in SrTiO3.
The effect of a small dose of gamma irradiation on transport characteristics of the two-dimensional electron gas (2DEG) in heterostructures was investigated. It is shown that the carrier concentration remains practically unchanged after an irradiation dose of , while the 2DEG mobility exhibits a considerable increase. The results are explained within a model that takes into account the relaxation of elastic strains and structural-impurity ordering occurring in the barrier layer under irradiation.
We report the results of direct measurements and a theoretical investigation of the in-plane effective mass in the two-dimensional electron gas of nominally undoped AlGaN/GaN heterostructures with a different degree of quantum confinement. It is shown that in most cases the conduction band nonparabolicity effect is overestimated and the electron wave-function penetration into the barrier layer should be taken into account. The contribution of the wave-function hybridization is determined to play the dominant role. The band edge effective mass value is deduced to be .
In this work, we report about the optimization of the spectral emission characteristic of a gas discharge plasma source for high-resolution extreme ultraviolet (EUV) interference lithography based on achromatic Talbot self-imaging. The working parameters of the source are optimized to achieve a required narrowband emission spectrum and to fulfill the necessary coherence and intensity requirements. The intense transitions around 11 nm in a highly ionized xenon plasma are chosen to provide the working wavelength. This allows us to increase the available radiation intensity in comparison with an in-band EUV xenon emission at 13.5 nm and opens up the possibility to strongly suppress the influence of the transitions at wavelengths between 12 and 16 nm utilizing a significant difference in conditions for optical thickness between and transitions. The effect is achieved by using the admixture of argon to the pinch plasma, which allows keeping the plasma parameters approximately constant while, at the same time, reducing the density of xenon emitters. It is demonstrated that with this approach it is possible to achieve a high intensity 11 nm EUV radiation with a bandwidth of 3%–4% without the use of multilayer mirrors or other additional spectral filters in the vicinity of the working wavelength. The achieved radiation parameters are sufficient for high-performance interference lithography based on the achromatic Talbot effect.