Natural fiber composites (NFC) are eco-friendly alternatives to synthetic polymers. However, some intrinsic natural fillers’ properties hinder their widespread implementation as reinforcement in polymeric matrices and require further investigation. In the scope of this study, the thermal, rheologic, mechanical (tension and flexural modes), and morphological properties, as well as the water absorption and dimensional stability of the NF polypropylene (PP)-based injection molded composites reinforced with rice husk (rh) and olive pits (op) of 20 wt.% and 30% wt.%, respectively, were investigated. The results suggest that the higher content of the rice husk and olive pits led to a similar reduction in the melt flow index (MFI), independent of the additive type compared to virgin polypropylene (PPv). The melting and crystallization temperatures of the PPrh and PPop composites did not change with statistical significance. The composites are stiffer than the PP matrix by up to 49% and possess higher mechanical strength in the tension mode at the expense of decreased ductility. PPrh and PPop have a superior flexural modulus in the bending mode, while the flexural strength improvement was accomplished for the PP30%rh. The influence of the fibers’ distribution in the bulk of the parts on their mechanical performance was confirmed based on a non-localized morphology evaluation, which constitutes a novelty of the presented research. The dimensional stability of the composites was improved as the linear shrinkage in the flow direction was decreased by 49% for PPrh and 30% for PPop, positively correlating with an increase in the filler content and stiffness. PPop was less susceptible to water sorption than PPrh due to fibers’ composition and larger surface-to-area volume ratios.
Agro-waste fibres for polymer composite reinforcement have gained increased interest in industry and academia as a more sustainable alternative to synthetic fibres. However, natural fibre composite (NFC) hygroscopicity is still an issue that needs to be solved. This work investigates how prolonged exposure to water affects the properties of the polypropylene (PP)-based injection-moulded composites reinforced with different contents of rice husk (rh) and olive pit (op) fibres. Both rh and op composites became more hydrophilic with increased fibre charge due to the affinity of cellulose and hemicellulose OH groups. Meanwhile, lignin contributes to the protection of the composites from thermo-oxidative degradation caused by water immersion. The PPrh composites had a higher saturation water content of 1.47% (20 wt.% rh) and 2.38% (30 wt.% rh) in comparison to PPop composites with an absorption of 1.13% (20 wt.% op) and 1.59% (30 wt.% op). The tensile elastic modulus has slightly increased, at the cost of the increased saturated composites’ rigidity, in composites with 30% rh and op fibre content (up to 13%) while marginally decreasing (down to 8%) in PP30%op compared to unsaturated counterparts. A similar trend was observed for the flexural modulus, enhanced up to 18%. However, rh and op composites with 30% fibre content ruptured in bending, highlighting their fragility after hydrolytic ageing.
The work reported here intends to identify and mitigate the causes for failure in a plastic faucet holder, a part of an integral float faucet with a well-documented history of fracture occurrence. A methodology for the identification of hidden internal defects in plastic parts and the elaboration of the required corrective actions towards quality improvement is, therefore, presented. Firstly, part defects were identified via injection moulding process numerical simulation. The latter has enabled the prediction of an excessive volumetric shrinkage at the core of the faucet holder, highlighting the presence of internal voids and, hence, the possible deterioration of the load-bearing capacity. The supposition was later confirmed by X-ray topography scans. Part reengineering, consisting of localized thickness reduction, was the option chosen for decreasing the high shrinkage at the core. For validation purposes, structural analyses were carried out, with and without accounting for the injection moulding processing history. The results obtained during part structural analysis have enabled us to conclude that, when taking into account the residual stresses generated during injection moulding, the analysis more closely reflects the experimental data and allows us to implicitly envisage the propensity to fracture. Moreover, the part modifications, undertaken during the faucet holder reengineering, led to the reduction of the cumulative (processing and imposed by load) stresses by 50%, when compared to the original design analysed.
Innovative toilets can save resources, but have higher embodied impacts associated with materials and electronic components. This article presents an environmental life-cycle assessment (LCA) of an innovative multifunctional toilet (WashOne) for two alternative configurations (with or without washlet), comparing its performance with those of conventional systems (toilet and bidet). Additionally, two scenario analyses were conducted: (i) user behavior (alternative washlet use patterns) and (ii) user location (Portugal, Germany, the Netherlands, Sweden and Saudi Arabia). The results show that the WashOne with washlet has a better global environmental performance than the conventional system, even for low use. It also reveals that the use phase has the highest contribution to impacts due to electricity consumption. User location analysis further shows that Sweden has the lowest environmental impact, while Germany and the Netherlands have the highest potential for impact reduction when changing from a conventional system to the WashOne. Based on the overall results, some recommendations are provided to enhance the environmental performance of innovative toilet systems, namely the optimization of the washlet use patterns. This article highlights the importance of performing a LCA at an early stage of the development of innovative toilets by identifying the critical issues and hotspots to improve their design and performance.
Agro-waste fibres for polymer composite reinforcement have gained increased interest in industry and academia as a more sustainable alternative to synthetic fibres. However, natural fibre composites (NFC) hygroscopicity is still an issue that needs to be solved. This work investigates how prolonged exposure to water affects the properties of the polypropylene (PP)--based injection moulded composites reinforced with different contents of rice husk (rh) and olive pit (op) fibres. Both rh and op composites became more hydrophilic with increased fibre charge due to the affinity of cellulose and hemicellulose OH groups. Meanwhile, lignin contributes to the protection of the composites from thermo-oxidative degradation caused by water immersion. The PPrh composites had a higher saturation water content of 1.47% (20 wt.% rh) and 2.38 (30 wt.% rh) in comparison to PPop composites with absorption of 1.13% (20 wt.% op) and 1.59% (30 wt.% op). Tensile elastic modulus has slightly increased, at the cost of increased saturated composites' rigidity, in composites with 30% rh and op fibre content (up to 13%) while marginally decreasing (down to 8%) in PP30%op compared to unsaturated counterparts. A similar trend was observed for the flexural modulus, enhanced up to 18%. However, rh and op composites with 30% fibre content ruptured in bending, highlighting their fragility after hydrolytic ageing.
Previous studies on healthy controls suggest the added value of thigh-based Electrocardiography (ECG), which collects data using sensors embedded in a toilet seat for unobtrusive signal acquisition. However, further evidence regarding its clinical feasibility is needed; with this work, we investigated three complementary aspects: signal quality, morphological correlation with standard ECG leads, and the system’s potential for heart rate variability (HRV) analysis in patients undergoing aortic valve replacement. This work was divided into two main phases. In the first, 32 healthy volunteers underwent simultaneous ECG recordings using both a standard 12-lead ECG system and the thigh-based system. Signal Quality Index (SQI) analysis revealed that 56.25% of the experimental signals were classified as excellent, and over 62.5% of recordings showed a strong correlation with Lead I of the clinical ECG. These findings extend the state of the art by further characterising the quality and relevance of the captured signals. In the second phase, two patients with severe aortic stenosis were monitored before and after surgical valve replacement. HRV metrics derived from the thigh-based ECG captured distinct autonomic responses: one patient showed significant postoperative improvement in global and parasympathetic modulation (increased SDNN, RMSSD, and Sample Entropy), while the other exhibited reduced variability and complexity, potentially indicating impaired autonomic recovery. These results highlight the feasibility of thigh-based ECG data acquisition for passive, longitudinal cardiac health monitoring in everyday environments and its applicability for pre- and postoperative autonomic assessment.