This study develops a ternary Fe-based geopolymer system composed of metakaolin (MK), red mud (RM), and fly ash (FA) for the preparation of sustainable water-retaining subgrade materials for sponge-city roadbed applications. Unlike conventional formulations primarily designed for structural strength or rapid permeability, the proposed MK–FA–RM system was designed to improve water-storage capacity while maintaining adequate mechanical support and environmental compatibility. In this ternary system, MK provides highly reactive aluminosilicate species for geopolymer network formation, RM introduces Fe-bearing phases and enhances industrial solid-waste utilization, and FA contributes to particle packing, workability, and resource efficiency. A constrained ternary mixture design implemented using Design-Expert software was adopted to optimize precursor proportions. Within the investigated compositional range, the fitted first-order mixture model showed acceptable statistical adequacy for preliminary composition screening (R² = 0.86). The optimal blend (60% MK, 30% RM, and 10% FA) achieved a 7-day compressive strength of 8.37 MPa and a water retention rate of 35.3% under ambient curing conditions, satisfying the strength requirement considered for the target subgrade/base-layer application. Microstructural and phase analyses suggest that the synergistic interaction of the three precursors promoted Fe-modified aluminosilicate gel formation together with conventional geopolymer gel products, while improving matrix continuity and preserving interconnected pore space for water storage. This multiscale structural effect helps explain how the material achieved a balance between water retention capacity and mechanical support. Under the tested conditions, the material maintained acceptable residual strength after short-term exposure to water, acid, and sulfate-containing solutions. Life-cycle assessment indicated a 70% reduction in CO₂ emissions compared with ordinary Portland cement, while pilot-scale cost analysis showed a 39% lower production cost than MetaMax-based geopolymer materials. Pilot-scale application further demonstrated the constructability and water-regulation potential of the material in practical environments. Overall, the proposed ternary Fe-based geopolymer demonstrates that Fe-rich industrial wastes can be engineered into low-carbon and economically viable water-retaining subgrade materials that balance hydraulic regulation, structural adequacy, and sustainability. Nevertheless, long-term durability, cyclic loading performance, and direct nanoscale characterization of Fe-bearing gel evolution still require further investigation.

Polymer-based wastewater disinfection, which is typically performed using chemical oxidation or irradiation, can result in various toxic byproducts and corrosion under harsh environments. This study introduces a robust bio-adsorbent prepared from naturally abundant polydopamine-modified medical stone (MS@PDA) for the high-efficiency removal of bacteria from water. The PDA nanocoating can be easily applied through an in situ self-polymerization process, resulting in a considerably high bacterial adsorption capacity of 6.6 k pcs mm⁻² for Staphylococcus aureus. A cyclic flow-through dynamic filtration and a disinfection system was implemented using an MS@PDA porous filter with an average pore size of 21.8 ± 1.4 µm and porosity of ~83%, achieving a 5.2–6.0-fold enhancement in the cumulative removal efficiency for MS@PDA₂. The underlying mechanisms were elucidated through the synergistic effects of interfacial bio-adsorption and size-dependent interception. Notably, the bacteria captured on the surface could be killed using the enhanced photothermal effects of the PDA nanocoating and the inherent antimicrobial properties of the mineral stone. Thus, this study not only provides a new type of advanced bio-adsorbent but also provides new perspectives on an efficient and cost-effective approach for sustainable wastewater treatment.

The utilization of dredged sediment (DS) as a transformative material in building applications presents an ideal consumption strategy. This study endeavors to create a novel ceramsite lightweight aggregate (LWA) through the co-sintering of DS and rice husks (RHs), further integrating this LWA into the construction of pervious concrete. Results revealed that the optimum production procedure for the DS-based LWA incorporated a 21% RH addition, a sintering temperature of 1100 °C, and a sintering duration of 21 min. Notably, the optimal ceramsite LWA, denoted as SDC-H, exhibited a cylinder compressive strength of 28.02 MPa and an adsorption efficiency for Pb²⁺ of 94.33%. Comprehensive analysis (encompassing bulk density, cylinder compressive strength, water absorption, and the leaching concentrations of heavy metals) confirmed that SDC-H impacted the specification threshold of high-strength light aggregate derived from solid waste (T/CSTM 00548-2022). Substituting 50% of SDC-H led to a diminution in the mechanical properties but an improvement in the dynamic adsorption capacity of the innovative pervious concrete, registering a mechanical strength of 26.25 MPa and a cumulative adsorption capacity for Pb²⁺ of 285 mg/g. These performances of pervious concrete containing 50% SDC-H might correlate with the evolution of an interconnected and open-pore structure.

Municipal solid waste incineration fly ash (MSWIFA) can be reused as an admixture in cementitious materials, but its low activity limits its utilization as a resource. In this study, we systematically investigated the mineral and grinding characteristics of MSWIFA and then studied its pretreatment and activation via mechanical force–surface modification. The results indicate that the fineness and angle of repose of MSWIFA during grinding are inversely proportional to grinding time, while specific surface area and powder fluidity increase. Agglomeration occurs in the later stage, and particle size fluctuates. Gray correlation analysis shows that MSWIFA powder with a particle size of 16–45 μm contributes most to compressive strength improvement. The composite surface modifier TEA-STPP benefits grinding, shortens ball-milling time, and increases active particle size content, thereby promoting hydration activity. The best process regarding the modifier was determined. MSWIFA and blast furnace slag (BFS) accelerate early hydration of ordinary Portland cement (OPC) and increase its reaction participation, promoting the generation of calcium chloroaluminate (Friedel’s salt) and monosulfate-aluminate phases (SO₄-AFm) and significantly enhancing the hydration of tricalcium aluminate (C₃A) in OPC.

To alleviate the eutrophication in the Wuliangsuhai watershed and evaluate the pollutant reduction performance of ecological drainage ditches in the Hetao Irrigation District, a controlled field simulation experiment was conducted using synthetic agricultural return-flow water formulated from long-term monitoring data. Three leguminous plant treatments, two microbial substrate treatments, and one control were established to compare the migration and transformation of total nitrogen (TN), total phosphorus (TP), and chemical oxygen demand (COD) in overlying water, sediment, and plants under different hydraulic retention time intervals (0–6 h, 6–12 h, and 12–18 h). The results showed that plant treatments generally improved conventional water quality indicators, with increased pH and dissolved oxygen (DO) and decreased electrical conductivity, salinity, and total dissolved solids, whereas microbial substrate treatments tended to reduce DO. Pollutant reduction performance differed among treatments. Medicago sativa showed the strongest TN removal from overlying water, Microbial biological rope exhibited the best TP removal from overlying water, and Melilotus suaveolens performed best in COD reduction. Among all plant treatments, Astragalus laxmannii exhibited the most stable overall performance and a relatively strong integrated capacity for nitrogen and phosphorus retention. Most TN and TP reduction in overlying water and sediment occurred during the initial hydraulic retention time interval of 0–6 h, whereas TN plant uptake became more evident during 12–18 h. These findings suggest that ecological drainage ditches vegetated with locally adapted leguminous species have potential to mitigate agricultural non-point source pollution in arid irrigation districts. In particular, Astragalus laxmannii appears to be a promising candidate for ecological ditch design in the Hetao Irrigation District. However, this study was conducted under controlled synthetic return-flow conditions rather than with actual field drainage water, and no tracer-based hydrodynamic verification was performed; therefore, the reported hydraulic retention time effects and treatment efficiencies should be interpreted cautiously. Further field-scale validations under real drainage, seasonal variation, and long-term operation conditions are still needed.