Hydrogen, as a renewable and clean energy carrier, has the potential to play an important role in carbon reduction. Crucial to achieving this is the ability to produce clean sources of hydrogen and to store hydrogen safely. With the rapid development of the hydrogen industry, the number of hydrogen refueling stations (HRS) is increasing. However, hydrogen safety at HRS is of great concern due to the high risk of hydrogen leakage during storage. This study focused on an integrated hydrogen production and refueling station (IHPRS) in Weifang, China, and numerically simulated a hydrogen leakage accident in its storage area. The effects of the leakage aperture, the leakage direction and the ambient wind direction and speed on the leakage and dissipation characteristics of hydrogen were investigated. The results showed that the volume, mass and dissipation time of the flammable hydrogen cloud (FHC) increased with an increase in the leakage aperture. The installation of a canopy or densely packed equipment near the hydrogen storage area will seriously hinder the dissipation of the FHC. Ambient winds in the opposite direction of the leakage may cause high-concentration hydrogen to accumulate near the hydrogen storage tanks and be difficult to dissipate, seriously threatening the safety of the integrated station.

Compared with gaseous hydrogen at ambient temperature, liquid hydrogen (LH₂) possesses a higher volumetric energy density and is therefore regarded as one of the most economically viable hydrogen storage and transportation options. However, the extremely large temperature difference between the storage temperature of LH₂ and the ambient environment may give rise to serious safety hazards once a leakage accident occurs. Focusing on an integrated hydrogen production and refueling station (IHPRS), this study investigates the suppression effect of a novel synergistic protection system—combining a barrier wall and an air curtain—on LH₂ leakage and dispersion. By comparing the dispersion distances of hydrogen clouds under different barrier wall–air curtain configurations, the optimal synergistic structure was identified as a barrier wall with a planar size of 36 m × 12 m and a height of 3 m, combined with an air curtain velocity of 40 m/s. The reliability of this structure is further evaluated under practical influencing factors: under varying natural wind conditions, the maximum downwind dispersion distance is reduced by up to 58.02%; at a flash evaporation mass fraction of 20%, horizontal dispersion is suppressed by 42.18% and 33.17% in the X- and Z-directions, respectively; and at a leakage mass flow rate of 5.15 kg/s, the X-direction dispersion distance is reduced by 33.88% with a 40.14% increase in cloud height. The results show that the proposed barrier wall–air curtain synergistic protection structure can effectively alter the dispersion path of the FHC (refers to the hydrogen cloud with a volume concentration within the flammable range between 4 and 75% vol) formed by LH₂ leakage, shorten the hazardous downwind distance, and enhance the vertical dispersion of the FHC. These findings provide theoretical support and safety guidance for the risk control of LH2 leakage accidents in IHPRS.