The dissolution of CO₂ in seawater in the form of bicarbonate ions is an attractive alternative to storage in geological formations, on the condition that the storage is stable over long periods and does not harm the marine environment. In this work, we focus on the long-term chemical stability of CO₂ absorbed in seawater as bicarbonate by monitoring the physico-chemical properties of the solutions (pH, dissolved inorganic carbon and alkalinity) in six different sets of experiments on both natural and artificial seawater lasting up to three months. The bicarbonate treatment of natural seawater consists of mixing it with pre-equilibrated solutions obtained from the reaction of CO₂ and Ca(OH)₂, with the same pH as natural seawater. This was achieved with a pilot plant working with tons of seawater, while small-scale laboratory experiments were carried out by adding sodium bicarbonate to artificial seawater solutions. If the increase in the overall carbon concentration in the final mixture does not exceed a critical threshold (about 1000–1500 μmol/L), the resulting bicarbonate-rich solutions are found to be stable for over three months.

The deployment of carbon dioxide removal (CDR) processes is required, as well as strong and immediate emission reductions, to limit the global temperature increase “well below to 2°C above pre-industrial levels” as required by the Article 2 of the Paris Agreement.Among the CDR processes, ocean alkalinity enhancement (OAE) allows to remove CO2 from the atmosphere and simultaneously to counteract the ongoing ocean acidification caused by the increased CO2 atmospheric concentration. In the framework of the DESARC (DEcreasing Seawater Acidification Removing Carbon) MARESANUS research project, different strategies to produce decarbonized slaked lime (SL), i.e. Ca(OH)2, and to discharge it in the seawater have been evaluated.The feasibility and the potential of OAE were evaluated at the global scale and at the Mediterranean Sea basin scale. Two different logistic scenarios for the discharge of SL were analyzed: new dedicated ships, and partial load on modified existing dry bulk and container ships. The data on the existing global fleet of vessels and marine routes has been elaborated to assess the potential discharge of SL.Through the life-cycle assessment methodology, the efficiency of removing CO2 from the atmosphere was evaluated, as well as other potential environmental impacts connected to SL production and transport. The “cradle-to-grave” approach has been applied to different configurations of the process, that consider both biomass gasification and the use of renewables as a source of energy for limestone calcination, as well as eventual CO2/H2 separation and CO2 storage.The data collected for the life cycle inventory were mainly obtained from the preliminary design of the process and the scientific literature, as well as from the ecoinvent database. According to the environmental footprint method implemented in SimaPro software, sixteen impact categories for assessing the burdens on the environment and human are evaluated, with a particular focus on Climate change, Land use,  and Mineral and metals use.The results show that for all the analyzed configurations, the process has a potential negative impact on the Climate change category, i.e. there is a benefit for the environment in terms of CO2 removal from the atmosphere. Since the avoided impacts are related to the source for hydrogen, the type of avoided source has a relevant role and is subjected to a sensitivity analysis.Finally, the availability of limestone for the large-scale development of ocean alkalinisation have been evaluated, considering in particular the deposits of pure limestone near the coastlines, that  could minimize logistic and transportation activities.Results show that pure carbonate potential resources are of several trillion tons and are not a constraint for the development of global-scale ocean liming. A large part of pure limestone resources is nearby the coastline, in areas with no or low vegetation cover, mainly in North Africa and Iran. Global limestone yearly production is similar to coal, and the required upscaling compared to the current extraction rate is far lower for limestone than for other materials considered for OAE, such as olivine, magnesite and brucite.

The dissolution of CO₂ in seawater in the form of bicarbonate ions is an attractive alternative to the storage in geological formations, on the conditions that the storage is stable over long times and does not harm the marine environment. In this work, we focus on the long-term chemical stability of CO₂ absorbed in seawater as bicarbonate, by monitoring the physico-chemical properties of the solutions (pH, dissolved inorganic carbon and alkalinity), in six different sets of experiments on both natural and artificial seawater lasting up to three months. The bicarbonate treatment of natural seawater consists in pouring pre-equilibrated solutions obtained from the reaction of CO₂ and Ca(OH)₂. If the pre-equilibrated mixture does not exceed a critical threshold (ca. 1000-1500 mmol/L), the resulting bicarbonate-rich solutions can be stable for over three months.