Sentinel-2 is a constellation of two satellites launched by the European Space Agency (ESA), respectively on 23 June 2015 and 7 March 2017, to map geophysical parameters over land surfaces. ESA provides Level 2 bottom-of-atmosphere reflectance (BOA) products (ESA-L2A) for Europe, with plans for operational global coverage, as well as the Sen2Cor (S2C) offline processor. In this study, aerosol optical thickness (AOT), precipitable water vapour (WVP) and surface reflectance from ESA-L2A products are compared with S2C output when using identical input Level 1 radiance products. Additionally, AOT and WVP are validated against reference measurement. As ESA and S2C share the same input and atmospheric correction algorithm, it was hypothesized that they should show identical validation performance and that differences between products should be negligible in comparison to the uncertainty of retrieved geophysical parameters due to radiometric uncertainty alone. Validation and intercomparison was performed for five clear-sky growing season dates for each of three ESA-L2A tiles selected to span a range of vegetation and topography as well as to be close to the AERONET measurement site. Validation of S2C (ESA) products using AERONET site measurements indicated an overall root mean square error (RMSE) of 0.06 (0.07) and a bias of 0.05 (0.09) for AOT and 0.20 cm (0.22 cm) and the bias was −0.02 cm (−0.10 cm) for WVP. Intercomparison of S2C-L2A and ESA-L2A showed an overall agreement higher than 99% for scene classification (SCL) maps and negligible differences for WVP (RMSE under 0.09 and R² above 0.99). Larger disagreement was observed for aerosol optical thickness (AOT) (RMSE up to 0.04 and R² as low as 0.14). For BOA reflectance, disagreement between products depends on vegetation cover density, topography slope and spectral band. The largest differences were observed for red-edge and infrared bands in mountainous vegetated areas (RMSE up to 4.9% reflectance and R² as low as 0.53). These differences are of similar magnitude to the radiometric calibration requirements for the Sentinel 2 imager. The differences had minimal impact of commonly used vegetation indices (NDVI, NDWI, EVI), but application of the Sentinel Level 2 biophysical processor generally resulted in proportional differences in most derived vegetation parameters. It is recommended that the consistency of ESA and S2C products should be improved by the developers of the ESA and S2C processors.

Time series of vegetation biophysical variables (leaf area index (LAI), fraction canopy cover (FCOVER), fraction of absorbed photosynthetically active radiation (FAPAR), canopy chlorophyll content (CCC), and canopy water content (CWC)) were estimated from interpolated Sentinel-2 (S2-LIKE) surface reflectance images, for an agricultural region located in central Canada, using the Simplified Level 2 Product Prototype Processor (SL2P). S2-LIKE surface reflectance data were generated by blending clear-sky Sentinel-2 Multispectral Imager (S2-MSI) images with daily BRDF-adjusted Moderate Resolution Imaging Spectrometer images using the Prediction Smooth Reflectance Fusion Model (PSFRM), and validated using thirteen independent S2-MSI images (RMSE $\le$ 6%). The uncertainty of S2-LIKE surface reflectance data increases with the time delay between the prediction date and the closest S2-MSI image used for training PSFRM. Vegetation biophysical variables from S2-LIKE products are validated qualitatively and quantitatively by comparison to the corresponding vegetation biophysical variables from S2-MSI products (RMSE = 0.55 for LAI, ~10% for FCOVER and FAPAR, and 0.13 g/m² for CCC and 0.16 kg/m² for CWC). Uncertainties of vegetation biophysical variables derived from S2-LIKE products are almost linearly related to the uncertainty of the input reflectance data. When compared to the in situ measurements collected during the Soil Moisture Active Passive Validation Experiment 2016 field campaign, uncertainties of LAI (0.83) and FCOVER (13.73%) estimates from S2-LIKE products were slightly larger than uncertainties of LAI (0.57) and FCOVER (11.80%) estimates from S2-MSI products. However, equal uncertainties (0.32 kg/m²) were obtained for CWC estimates using SL2P with either S2-LIKE or S2-MSI input data.

Vegetation essential climate variables corresponding to the black-sky albedo (albedo), the fraction of absorbed photosynthetically active radiation (fAPAR), the fraction of canopy cover (fCOVER) and the leaf area index (LAI), as defined by the Global Climate Observing System, are produced for the United Kingdom at 20m resolution on a monthly basis from 2017 to 2023. Maps correspond to variables estimated from input Copernicus Sentinel-2 satellite imagery using the Landscape Evolution and Forecasting (LEAF) Toolbox implementation of the Simplified Level 2 Prototype Processor. The day of retrieval is also provided with each monthly map. Uncertainty estimates are provided based on validation over North America. These products have not been validated over the United Kingdom and are only available for research use.