We investigated the effect of electrolyte thickness and operating temperature on the heat and mass transfer characteristics of solid oxide fuel cells. We conducted extensive numerical simulations to analyze single cell performance of a planar solid oxide fuel cell (SOFC) with electrolyte thicknesses from 80 to 100 μm and operating temperatures between 700 °C and 800 °C. The commercial computational fluid dynamics (CFD) code was utilized to simulate the transport behavior and electrochemical reactions. As expected, the maximum power density increased with decreasing electrolyte thickness, and the difference became significant when the current density increased among different electrolyte thicknesses at a fixed temperature. Thinner electrolytes are beneficial for volumetric power density due to lower ohmic loss. Moreover, the SOFC performance enhanced with increasing operating temperature, which substantially changed the reaction rate along the channel direction. This study can be used to help design SOFC stacks to achieve enhanced heat and mass transfer during operation.

The present study established the two-dimensional axisymmetric model for a freestanding circular cell of the low-temperature micro-solid oxide fuel cell (µ-SOFC) that is composed of platinum (Pt) electrodes and a yttria-stabilized zirconia (YSZ) electrolyte. The only membrane electrode assembly (MEA) was constructed for the numerical simulation in order to avoid the meshing problem with a very high aspect ratio of the submicron layers. We considered the charge and species conservation equations and electrode kinetics to elucidate the intricate phenomena inside the µ-SOFC. The extensive numerical simulations were carried out by using the commercial code to predict the effect of operating temperature and electrolyte thickness on the electrochemical performance of µ-SOFC. Our numerical model was calibrated with the results from experiments, and we provided the average cell current density and overpotentials with respect to the electrolyte thickness and the operating temperature. It was found that the electrochemical performance increased with the increase in operating temperature, owing to both rapid electrochemical reactions and ionic conduction, even in µ-SOFC. Moreover, the major voltage loss of µ-SOFC at low-temperature was caused by the cathodic activation overpotential.

This study investigates numerically gaseous CO₂ leakage characteristics inside the containers of a transport ship and examines thermal effects on the structural damage that might happen in the containers. First, with consideration of the phase change, the ejected mass flow rate was estimated using the commercial code of DNV PHAST. Based on this estimated mass flow rate, we introduced an effective area model for accounting for the fast evaporation of liquefied CO₂ occurring in the vicinity of a crack hole. Using this leakage modeling, along with a concept of the effective area, the computational fluid dynamics (CFD) simulations for analyzing transient three-dimensional characteristics of gas propagation in a confined space with nine containers, as well as the thermal effect on the walls on which the leaking gas impinges, were conducted. The commercial code, ANSYS FLUENT V. 17.0, was used for all CFD simulations. It was found that there are substantial changes in the pressure and temperature of the gas mixture for different crack sizes. The CO₂ concentration at human nasal height, a measure of clear height for safety, was also estimated to be higher than the safety threshold of 10% within 200 s. Moreover, very cold gas created by the evaporation of liquefied CO₂ can cool the cargo walls rapidly, which might cause thermal damage.