Wintertime ammonium nitrate aerosol pollution is a severe air quality issue affecting both developed and rapidly urbanizing regions from Europe to East Asia. In the United States, it is acute in western basins subject to inversions that confine pollutants near the surface. Measurements and modeling of a wintertime pollution episode in Salt Lake Valley, Utah, demonstrate that ammonium nitrate is closely related to photochemical ozone through a common parameter, total odd oxygen, Ox,total. We show that the traditional nitrogen oxide and volatile organic compound (NOx‐VOC) framework for evaluating ozone mitigation strategies also applies to ammonium nitrate. Despite being nitrate‐limited, ammonium nitrate aerosol pollution in Salt Lake Valley is responsive to VOCs control and, counterintuitively, not initially responsive to NOx control. We demonstrate simultaneous nitrate limitation and NOx saturation and suggest this phenomenon may be general. This finding may identify an unrecognized control strategy to address a global public health issue in regions with severe winter aerosol pollution.
23 February 2018 in Journal of Geophysical Research: Atmospheres
Numerous mountain valleys experience wintertime particulate pollution events, when persistent cold air pools (PCAPs) develop and inhibit atmospheric mixing, leading to the accumulation of pollutants. Here we examine the relationships between trace gases and criteria pollutants during winter in Utah's Salt Lake Valley, in an effort to better understand the roles of transport versus chemical processes during differing meteorological conditions as well as insights into how targeted reductions in greenhouse gases will impact local air quality in varying meteorological conditions. CO2 is a chemically inert gas that is coemitted during fossil fuel combustion with pollutants. Many of these coemitted pollutants are precursors that react chemically to form secondary particulate matter. Thus, CO2 can serve as a stable tracer and potentially help distinguish transport versus chemical influences on pollutants. During the winter of 2015–2016, we isolated enhancements in CO2 over baseline levels due to urban emissions (“CO2ex”). CO2ex was paired with similar excesses in other pollutant concentrations. These relationships were examined during different wintertime conditions and stages of pollution episodes: (a) Non‐PCAP, (b) beginning, and (c) latter stages of an episode. We found that CO2ex is a good indicator of the presence of gaseous criteria pollutants and a reasonable indicator of PM2.5. Additionally, the relationships between CO2ex and criteria pollutants differ during different phases of PCAP events which provide insight into meteorological and transport processes. Lastly, we found a slight overestimation of CO:CO2 emission ratios and a considerable overestimation of NOx:CO2 by existing inventories for the Salt Lake Valley.
The Utah Urban CO2 Network (UUCON) is a network of near-surface atmospheric carbon dioxide (CO2) measurement sites aimed at quantifying long-term changes in urban and rural locations throughout northern Utah since 2001. We document improvements to UUCON made in 2015 that increase measurement precision, standardize sampling protocols, and expand the number of measurement locations to represent a larger region in northern Utah. In a parallel effort, near-surface CO2 and methane (CH4) measurement sites were assembled as part of the Uintah Basin greenhouse gas (GHG) network in a region of oil and natural gas extraction located in northeastern Utah. Additional efforts have resulted in automated quality control, calibration, and visualization of data through utilities hosted online (https://air.utah.edu, last access: 22 August 2019). These improvements facilitate atmospheric modeling efforts and quantify atmospheric composition in urban and rural locations throughout northern Utah. Here we present an overview of the instrumentation design and methods within UUCON and the Uintah Basin GHG networks as well as describe and report measurement uncertainties using a broadly applicable and novel method. Historic and modern data described in this paper are archived with the National Oceanic and Atmospheric Administration's (NOAA) National Centers for Environmental Information (NCEI) and can be found at https://doi.org/10.7289/V50R9MN2 (Mitchell et al., 2018c) and https://doi.org/10.25921/8vaj-bk51 (Bares et al., 2018a) respectively.
Paleoenvironmental reconstructions are important for understanding the influence of long-term climate variability on ecosystems and landscape disturbance dynamics. In this paper we explore the linkages among past climate, vegetation, and fire regimes using a high-resolution pollen and charcoal reconstruction from Morris Pond located on the Markagunt Plateau in southwestern Utah, USA. A regime shift detection algorithm was applied to background charcoal accumulation to define where statistically significant shifts in fire regimes occurred. The early Holocene was characterized by greater amounts of summer precipitation and less winter precipitation than modern. Ample forest fuel and warm summer temperatures allowed for large fires to occur. The middle Holocene was a transitional period between vegetation conditions and fire disturbance. The late Holocene climate is characterized as cool and wet reflecting an increase in snow cover, which reduced opportunities for fire despite increased availability of fuels. Similarities between modern forest fuel availability and those of the early Holocene suggest that warmer summers projected for the 21st century may yield substantial increases in the recurrence and ecological impacts of fire when compared to the fire regime of the last millennium.
Vehicle emissions are a major source of pollution in urban communities and idling may contribute up to 34% or more to local air pollution levels. Reduced idling has been found to be an effective policy tool for improving air quality, especially around schools, where it may also improve outcomes for asthmatic children. We studied two anti-idling campaigns in Salt Lake County, Utah to understand if reduced engine idling leads to behavioral change and subsequent reduction in traffic-related air pollution exposure of the related school. We found a 38% decrease in idling time following an anti-idling campaign and an 11% decrease in the number of vehicles idling at the school drop-off zones. The air quality measurements showed improvement in the middle of the campaign, but seasonal variability as well as atmospheric inversion events had substantial effects on overall ambient pollutant concentrations. This study provides an encouraging starting point to develop more effective anti-idling campaigns to protect the health of children, school staff, and the surrounding community.
Although there ismounting evidence that suggests that air pollution is impactful to human health and educational outcomes, this is especially problematic in schools with higher air pollution levels. To understand whether all schools in an urban area are exposed to similar outdoor air quality and whether school infrastructure protects children equally indoors, we installed research-grade sensors to observe PM2.5 concentrations in indoor and outdoor settings to understand how unequal exposure to indoor and outdoor air pollution impacts indoor air quality among high- and low-income schools in Salt Lake City, Utah. These data and resulting analysis show that poor air quality may impact school settings and the potential implications with respect to environmental inequality. Based on this approach, we found that during atmospheric inversions and dust events, there was a lag ranging between 35 and 73 min for the outdoor PM2.5 concentrations to follow a similar temporal pattern as the indoor PM2.5. This lag has policy and health implications and may help to explain rising concerns regarding reduced educational outcomes related to air pollution in urban areas.