ZnO nanopowders were produced using microwave processing of a precipitate and applied as a photoanode for photoelectrochemical water splitting. Two different surfactants, cetyltrimethylammonium bromide (CTAB) as the cationic and Pluronic F127 as the non-ionic one, were employed to in situ adjust the surface-to-bulk defect ratio in the ZnO crystal structure and further to modify the photo(electro)catalytic activity of the ZnO photoanode. The crystal structure, morphological, textural, optical and photo(electro)catalytic properties of ZnO particles were studied in detail to explain the profound effects of the surfactants on the photoanode activity. The ZnO/CTAB photoanode displayed the highest photocurrent density of 27 mA g⁻¹, compared to ZnO (10.4 mA g⁻¹) and ZnO/F127 photoanodes (20 mA g⁻¹) at 1.5 V vs. SCE in 0.1 M Na₂SO₄ under visible illumination of 90 mW cm⁻². A significant shift of the overpotential toward lower values was also observed when photoanodes were illuminated. The highest shift of the overpotential, from 1.296 to 0.248 V vs. SCE, was recorded when the ZnO/CTAB photanode was illuminated. The ZnO/CTAB photoanode provides efficient charge transfer across the electrode/electrolyte interface, with a longer lifetime of photogenerated electron–hole pairs and reduced possibility of charge recombination. The photoconversion efficiency was improved from 1.4% for ZnO and 0.9% for ZnO/F127 to 4.2% for ZnO/CTAB at 0.510 mV. A simple procedure for the synthesis of ZnO particles with improved photo(electro)catalytic properties was established and it was found that even a small amount of CTAB used during processing of ZnO increases the surface-to-bulk defect ratio. Optimization of the surface-to-bulk defect ratio in ZnO materials enables increase of the absorption capacity for visible light, rendering of the recombination rate of the photogenerated pair, as well as increase of both the photocurrent density and photoconversion efficiency.

Plasma electrolytic oxidation (PEO) of aluminum in electrolytes containing CeO₂ and Eu₂O₃ powders in various concentrations was used for creating Al₂O₃ coatings doped with Ce³⁺ and Eu²⁺ ions. Phase and chemical composition, surface morphology, photoluminescence (PL) properties and energy transfer from Ce³⁺ to Eu²⁺ were investigated. When excited by middle ultraviolet radiation, Al₂O₃:Ce³⁺/Eu²⁺ coatings exhibited intense and broad emission PL bands in the ultraviolet/visible spectral range, attributed to the characteristic electric dipole 4f⁰5d¹→4f¹ transition of Ce³⁺ (centered at about 345 nm) and 4f⁶5d¹→4f⁷ transition of Eu²⁺ (centered at about 405 and 500 nm). Due to the overlap between the PL emission of Al₂O₃:Ce³⁺ and the PL excitation of Al₂O₃:Eu²⁺, energy transfer from Ce³⁺ sensitizer to the Eu²⁺ activator occurs. The energy transfer is identified as an electric dipole–dipole interaction. The critical distance between Eu²⁺ and Ce³⁺ ions in Al₂O₃ was estimated to be 8.6 Å by the spectral overlap method.

Plasma electrolytic oxidation of zirconium in citric acid was investigated using optical spectroscopy. A rich emission spectrum consisting of about 360 zirconium and 170 oxygen atomic and ionic lines was identified in the spectral regions 313–320, 340–516, and 626–640 nm. It was shown that the remaining features observed in the spectrum could be ascribed to various molecular species, which involve zirconium, oxygen, hydrogen, and carbon. The temperature of the plasma core ( T = 7500 ± 1000 K) was determined using measured Zr line intensities, and the temperature of peripheral plasma zone ( T = 2800 ± 500 K) was estimated from the intensity distribution within a part of an OH spectrum. The composition of the plasma containing zirconium, oxygen, and hydrogen, under assumption of local thermal equilibrium, was calculated in the temperature range up to 12 000 K and for pressure of 10⁵ and 10⁷ Pa, in order to explain the appearance of the observed spectral features.

MgAl and MgAl/ZnO coatings were prepared by plasma electrolytic oxidation (PEO) of AZ31 magnesium alloy in aluminate electrolyte (5 g/L NaAlO₂) without and with addition of ZnO particles in various concentrations. The MgAl coating was partially crystallized and contained MgO and MgAl₂O₄ phases. The addition of ZnO particles to aluminate electrolyte had no significant effect on the surface morphology of formed coatings, while the Zn content increased with ZnO particle concentrations. X-ray diffraction confirmed the incorporation of ZnO particles in the coatings. The photodegradation of methyl orange (10 cm³ of 8 mg/L) was used to measure the photocatalytic activity (PA) of MgAl and MgAl/ZnO coatings. The PA of MgAl coating after 8 h of irradiation was around 58%, while the PA of MgAl/ZnO coatings formed in aluminate electrolyte with the addition of ZnO particles in concentrations of 4 g/L, 8 g/L, and 12 g/L were around 69%, 86%, and 97%, respectively.

Copper-silver and cobalt-silver alloy nanoparticles deposited on reduced graphene oxide (CuAg/rGO and CoAg/rGO) were synthesized and examined as electrocatalysts for oxygen reduction reaction (ORR) and hydrogen peroxide reduction reaction (HPRR) in alkaline media. Characterization of the prepared samples was done by transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray diffraction analysis (XRD), and scanning electron microscopy with integrated energy-dispersive X-ray spectroscopy (SEM-EDS). CuAg/rGO and CoAg/rGO nanoparticles diameter ranged from 0.4 to 9.2 nm. The Ag loading was ca. 40 wt.% for both electrocatalysts, with that for Cu and Co being 35 and 17 wt.%, respectively. CoAg/rGO electrocatalyst showed a Tafel slope of 109 mV dec⁻¹, significantly lower than that for CuAg/rGO (184 mV dec⁻¹), suggesting faster ORR kinetics. Additionally, a higher diffusion current density was obtained for CoAg/rGO (−2.63 mA cm⁻²) than for CuAg/rGO (−1.74 mA cm⁻²). The average value of the number of electrons transferred during ORR was 2.8 for CuAg/rGO and 3.3 for CoAg/rGO electrocatalyst, further confirming the higher ORR activity of the latter. On the other hand, CuAg/rGO showed higher peak current densities (−3.96 mA cm⁻²) for HPRR compared to those recorded for CoAg/rGO electrocatalyst (−1.96 mA cm⁻²).