The development of anti-corrosion polymeric coatings has grown exponentially in the fields of material science, chemistry, engineering, and nanotechnology during the last century and has prompted the evolution of efficient characterization techniques. Nowadays, polymeric coatings represent a well-established protection system that provides a barrier between a metallic substrate and the environment. However, the increase in complexity and functionality of these coatings requires high-precision techniques capable of predicting failures and providing smart protection. This review summarizes the state of the art for the main electrochemical techniques, emphasizing devices that track the anti-corrosion properties of polymeric coatings from the macroscale to the nanoscale. An overview of the advances in accelerated corrosion testing and the electrochemical characterization of coatings is explored, including insights into their advantages and limitations. In addition, the challenges and potential applications of the theoretical approaches are summarized based on current knowledge. Finally, this work provides the reader with the trends and challenges of designing future technologies and models capable of tracking corrosion and predicting failures.

Transparent glass-ceramics have shown interesting optical properties for several photonic applications. In particular, compositions based on oxide glass matrices with fluoride crystals embedded inside, known as oxyfluoride glass-ceramics, have gained increasing interest in the last few decades. Melt-quenching is still the most used method to prepare these materials but sol-gel has been indicated as a suitable alternative. Many papers have been published since the end of the 1990s, when these materials were prepared by sol-gel for the first time, thus a review of the achievements obtained so far is necessary. In the first part of this paper, a review of transparent sol-gel glass-ceramics is made focusing mainly on oxyfluoride compositions. Many interesting optical results have been obtained but very little innovation of synthesis and processing is found with respect to pioneering papers published 20 years ago. In the second part we describe the improvements in synthesis and processing obtained by the authors during the last five years. The main achievements are the preparation of oxyfluoride glass-ceramics with a much higher fluoride crystal fraction, at least double that reported up to now, and the first synthesis of NaGdF₄ glass-ceramics. Moreover, a new SiO₂ precursor was introduced in the synthesis, allowing for a reduction in the treatment temperature and favoring hydroxyl group removal. Interesting optical properties demonstrated the incorporation of dopant ions in the fluoride crystals, thus obtaining crystal-like spectra along with higher efficiencies with respect to xerogels, and hence demonstrating that these materials are a suitable alternative for photonic applications.

This paper presents a review on the preparation of glass-ceramics (GCs) and, in particular, transparent GCs by the advanced processing technique of spark plasma sintering (SPS). SPS is an important approach to obtain from simple to complex nanostructured transparent GCs, full densification in a short time, and highly homogeneous materials for optical applications. The influence of the different processing parameters, such as temperature, pressure, sintering dwell time on the shrinkage rate, and final densification and transparency, are discussed and how this affects the glass material properties. Normally, transparent glass-ceramics are obtained by conventional melt-quenching, followed by thermal treatment. Additionally, the GC scan is produced by sintering and crystallization from glass powders. Hot pressing techniques (HP) in which the source of heating is high-frequency induction can be also applied to enhance this process. In the case of transparent ceramics and glass-ceramics, spark plasma sintering is a promising processing tool. It is possible to enhance the material properties in terms of its compactness, porosities, crystallization, keeping the size of the crystals in the nanometric scale. Moreover, the introduction of a high concentration of active gain media into the host matrix provides functional glass-ceramics systems with enhanced luminescence intensity through reducing non-radiative transitions like multi phonon relaxation (MPR) and cross relaxations (CR), thus providing longer lifetimes. More effort is needed to better understand the sintering mechanisms by SPS in transparent GC systems and optimize their final optical performance.

AZ31B Mg alloys were anodized at different potentials using an alkaline electrolyte. Then, an epoxy-alkyl silane sol reinforced with SiO₂ nanoparticles was prepared by sol–gel and deposited on top of the optimized anodic layers. 1-Methyl imidazole was added to the sol to promote a partial epoxy ring aperture and improve the condensation degree of the inorganic network. The results showed the curing temperature affects the inorganic polycondensation of the organic-inorganic network; this effect was analyzed by ²⁹Si and ¹³C solid-state NMR spectroscopy. Electrochemical impedance spectroscopy in 3.5 wt% NaCl solution revealed that the corrosion resistance is enhanced by the anodized process obtained for Mg alloy anodized at 100 V/2 min. However, a quick deterioration of the oxide film with immersion time was evident, showing a reduction of the protection efficiency (ηE%) of 76.5% after 16 h/immersion. The deposition of an epoxy-alkyl coating improved the ηE% up to 98.6% after 72 h/immersion. The proposed hybrid coating used for post-sealing the porous anodized Mg alloy looks like a good alternative protective barrier to control the corrosion process of Mg alloys. A suitable compromise between cross-linking network and curing temperature is necessary to obtain a good barrier coating.