A variety of mechanoluminescent (ML) materials have recently reinvigorated studies of luminescence activated by mechanical stress, but few practical applications have been demonstrated due to the destructive nature of the process. To overcome these shortcomings, elastico-mechanoluminescent (elastico-ML) materials, which generate luminescence under elastic deformation, have been suggested with a view to their use in practical devices. However, the weak brightness and limited white colour expression of these materials must be resolved before they can be employed in practical applications. Here, we report a wind-driven ML device that produces significant brightness and emits warm/neutral/cool white light over a range of colour temperatures from zinc sulphide (ZnS) microscopic particles embedded in a polydimethylsiloxane (PDMS) composite. Harnessing wind-activated mechanoluminescent devices in practical displays or lighting systems could pave the way to new environmentally friendly lights, which reduce energy waste and promote sustainability.
Two-dimensional (2D) materials exhibit enhanced physical, chemical, electronic, and optical properties when compared to those of bulk materials. Graphene demands significant attention due to its superior physical and electronic characteristics among different types of 2D materials. The bilayer graphene is fabricated by the stacking of the two monolayers of graphene. The twisted bilayer graphene (tBLG) superlattice is formed when these layers are twisted at a small angle. The presence of disorders and interlayer interactions in tBLG enhances several characteristics, including the optical and electrical properties. The studies on twisted bilayer graphene have been exciting and challenging thus far, especially after superconductivity was reported in tBLG at the magic angle. This article reviews the current progress in the fabrication techniques of twisted bilayer graphene and its twisting angle-dependent properties.
1 January 2022 in Journal of Colloid and Interface Science
The stacking order in layered transition-metal dichalcogenides (TMDCs) induces variations in the electronic and interlayer couplings. Therefore, controlling the stacking orientations when synthesizing TMDCs is desirable but remains a significant challenge. Here, we developed and showed the growth kinetics of different shapes and stacking orders in as-grown multi-stacked MoS2 crystals and revealed the stacking-order-induced interlayer separations, spin–orbit couplings (SOCs), and symmetry variations. Raman spectra in AA(A…)-stacked crystals demonstrated blueshifted out-of-plane (A1g) and in-plane (E2g1) phonon frequencies, representing a greater reduction of the van der Waals gap compared to conventional AB(A…)-stacking. Our observations, together with first-principles calculations, revealed distinct excitonic phenomena due to various stacking orientations. As a result, the photoluminescence emission was improved in the AA(A…)-stacking configuration. Additionally, calculations showed that the valence-band maxima (VBM) at the K point of the AA(A…)-stacking configuration was separated into multiple sub-bands, indicating the presence of stronger SOC. We demonstrated that AA(A…)-stacking emitted an intense second-harmonic signal (SHG) as a fingerprint of the more augmented non-centrosymmetric stacking and enabled SOC-induced splitting at the VBM. We further highlighted the superiority of four-wave mixing-correlated SHG microscopy to quickly resolve the symmetries and multi-domain crystalline phases of differently shaped crystals. Our study based on crystals with different shapes and multiple stacking configurations provides a new avenue for development of future optoelectronic devices.