Kinetic Inductance Detectors (KIDs) provide a promising solution to the problem of producing large format arrays of ultra sensitive detectors for astronomy. Traditionally KIDs have been constructed from superconducting quarter-wave resonant elements capacitively coupled to a co-planar feed line [1]. Photon detection is achieved by measuring the change in quasi-particle density caused by the splitting of Cooper pairs in the superconducting resonant element. This change in quasi-particle density alters the kinetic inductance, and hence the resonant frequency of the resonant element. This arrangement requires the quasi-particles generated by photon absorption to be concentrated at positions of high current density in the resonator. This is usually achieved through antenna coupling or quasi-particle trapping. For these detectors to work at wavelengths shorter than around 500 μm where antenna coupling can introduce a significant loss of efficiency, then a direct absorption method needs to be considered. One solution to this problem is the Lumped Element KID (LEKID), which shows no current variation along its length and can be arranged into a photon absorbing area coupled to free space and therefore requiring no antennas or quasi-particle trapping. This paper outlines the relevant microwave theory of a LEKID, along with theoretical and measured performance for these devices.

A dual mode, microstrip, microfluidic sensor was designed, built, and tested, which has the ability to measure a liquid's permittivity at 2.5 GHz and, simultaneously, compensate for temperature variations. The active liquid volume is small, only around $4.5~μL. The sensor comprises two quarter ring microstrip resonators, which are excited in parallel. The first of these is a microfluidic sensor whose resonant frequency and quality factor depend on the dielectric properties of a liquid sample. The second is used as a reference to adjust for changes in the ambient temperature. To validate this method, two liquids (water and chloroform) have been tested over a temperature range from 23 °C to 35 °C, with excellent compensation results.

In microwave chemistry there is a common misconception that small, highly conducting particles heat profusely when placed in a large microwave electric field. However, this is not the case; with the simple physical explanation that the electric field (which drives the heating) within a highly conducting particle is highly screened. Instead, it is the magnetic absorption associated with induction that accounts for the large experimental heating rates observed for small metal particles. We present simple principles for the effective heating of particles in microwave fields from calculations of electric and magnetic dipole absorptions for a range of practical values of particle size and conductivity. For highly conducting particles, magnetic absorption dominates electric absorption over a wide range of particle radii, with an optimum absorption set by the ratio of mean particle radius a to the skin depth δ (specifically, by the condition a = 2.41δ). This means that for particles of any conductivity, optimized magnetic absorption (and hence microwave heating by magnetic induction) can be achieved by simple selection of the mean particle size. For weakly conducting samples, electric dipole absorption dominates, and is maximized when the conductivity is approximately σ ≈ 3ωε₀ ≈ 0.4 S m⁻¹, independent of particle radius. Therefore, although electric dipole heating can be as effective as magnetic dipole heating for a powder sample of the same volume, it is harder to obtain optimized conditions at a fixed frequency of microwave field. The absorption of sub-micron particles is ineffective in both magnetic and electric fields. However, if the particles are magnetic, with a lossy part to their complex permeability, then magnetic dipole losses are dramatically enhanced compared to their values for non-magnetic particles. An interesting application of this is the use of very small magnetic particles for the selective microwave heating of biological samples.

The catalytic behavior of zeolite catalysts for the ammonia-based selective catalytic reduction (SCR) of nitrogen oxides (NO_X) depends strongly on the type of zeolite material. An essential precondition for SCR is a previous ammonia gas adsorption that occurs on acidic sites of the zeolite. In order to understand and develop SCR active materials, it is crucial to know the amount of sorbed ammonia under reaction conditions. To support classical temperature-programmed desorption (TPD) experiments, a correlation of the dielectric properties with the catalytic properties and the ammonia sorption under reaction conditions appears promising. In this work, a laboratory test setup, which enables direct measurements of the dielectric properties of catalytic powder samples under a defined gas atmosphere and temperature by microwave cavity perturbation, has been developed. Based on previous investigations and computational simulations, a resonator cavity and a heating system were designed, installed and characterized. The resonator cavity is designed to operate in its TM₀₁₀ mode at 1.2 GHz. The first measurement of the ammonia loading of an H-ZSM-5 zeolite confirmed the operating performance of the test setup at constant temperatures of up to 300 °C. It showed how both real and imaginary parts of the relative complex permittivity are strongly correlated with the mass of stored ammonia.

A miniaturized 2.4 GHz re-entrant cavity has been designed, manufactured and tested as a sensor for microfluidic compositional analysis. It has been fully evaluated experimentally with water and common solvents, namely methanol, ethanol, and chloroform, with excellent agreement with the expected behaviour predicted by the Debye model. The sensor’s performance has also been assessed for analysis of segmented flow using water and oil. The samples’ interaction with the electric field in the gap region has been maximized by aligning the sample tube parallel to the electric field in this region, and the small width of the gap (typically 1 mm) result in a highly localised complex permittivity measurement. The re-entrant cavity has simple mechanical geometry, small size, high quality factor, and due to the high concentration of electric field in the gap region, a very small mode volume. These factors combine to result in a highly sensitive, compact sensor for both pure liquids and liquid mixtures in capillary or microfluidic environments.

In this paper, we discuss the potential of using microwave techniques in the refinement of heavy fraction of petroleums such as bunker oil. After discussing the fundamental issues associated with conversion of microwave energy into heat, we present measurements of the dielectric properties of heavy oils at 2.45 GHz using a highly sensitive resonant cavity method, and also over a broader frequency range (100 MHz to 8 GHz) using a coaxial probe technique. We find that the dielectric loss is very small even in these heavy oils, but still may be sufficiently large to provide efficient conversion of microwave energy into heat on untreated samples, and could be massively enhanced by means of a microwave-absorbing additive (e.g., carbon black). We conclude by discussing the design of a suitable microwave actuator for heavy oil cracking within a flow process.