The possibility of recycling glass fibre-reinforced composites by using microwave pyrolysis was examined. A scrap blade from a wind turbine was fragmented and microwave-pyrolysed. The glass fibre recovered after pyrolysis represented 70% of the initial mass of glass fibre-reinforced composites. The tensile strength of the glass fibre recovered was measured after pyrolysis and compared to the tensile strength of untreated glass fibre. The test showed that the fibres lost about 25% of their tenacity. Non-woven fibre mats were prepared from the recovered fibres. Laminates were then prepared from the non-woven mats obtained, together with virgin glass fibre mats. Mechanical testing of the laminates showed that it is possible to prepare composites using 25 wt% of recycled fibres, with relatively good mechanical properties.
29 October 2017 in International Journal of Polymer Science
While citrus waste is abundantly generated, the disposal methods used today remain unsatisfactory: they can be deleterious for ruminants, can cause soil salinity, or are not economically feasible; yet citrus waste consists of various valuable polymers. This paper introduces a novel environmentally safe approach that utilizes citrus waste polymers as a biobased and biodegradable film, for example, for food packaging. Orange waste has been investigated for biofilm production, using the gelling ability of pectin and the strength of cellulosic fibres. A casting method was used to form a film from the previously washed, dried, and milled orange waste. Two film-drying methods, a laboratory oven and an incubator shaker, were compared. FE-SEM images confirmed a smoother film morphology when the incubator shaker was used for drying. The tensile strength of the films was 31.67 ± 4.21 and 34.76 ± 2.64 MPa, respectively, for the oven-dried and incubator-dried films, which is within the range of different commodity plastics. Additionally, biodegradability of the films was confirmed under anaerobic conditions. Films showed an opaque appearance with yellowish colour.
Extensive quantities of apple pomace are generated annually but its disposal is still challenging. This study addresses this issue by introducing a new, environmentally-friendly approach for the production of sustainable biomaterials from apple pomace, containing 55.47% free sugars and a water insoluble fraction, containing 29.42 ± 0.44% hemicelluloses, 38.99 ± 0.42% cellulose, and 22.94 ± 0.12% lignin. Solution casting and compression molding were applied to form bio-based films and 3D objects (i.e., fiberboards), respectively. Using glycerol as plasticizer resulted in highly compact films with high tensile strength and low elongation (16.49 ± 2.54 MPa and 10.78 ± 3.19%, respectively). In contrast, naturally occurring sugars in the apple pomace showed stronger plasticizing effect in the films and resulted in a fluffier and connected structure with significantly higher elongation (37.39 ± 10.38% and 55.41 ± 5.38%, respectively). Benefiting from the self-binding capacity of polysaccharides, fiberboards were prepared by compression molding at 100 °C using glycerol or naturally occurring sugars, such as plasticizer. The obtained fiberboards exhibited tensile strength of 3.02–5.79 MPa and elongation of 0.93%–1.56%. Possible applications for apple pomace biomaterials are edible/disposable tableware or food packaging.
5 January 2010 in Journal of Applied Polymer Science