The nucleation and growth of bubbles on homogeneous wetting surfaces have been extensively studied, but the intricate dynamics on hybrid wetting surfaces remain under-explored. This research aims to elucidate the impact of hybrid wettability on pool boiling heat transfer efficiency, specifically under downward-facing heating conditions. To this end, a series of hybrid wettability surfaces with varying hydrophilic and hydrophobic configurations are meticulously fabricated and analyzed. The study reveals distinctive interfacial phenomena occurring at the boundary between hydrophilic and hydrophobic regions during the boiling process. Experimental results indicate that surfaces with a higher proportion of hydrophilic to hydrophobic interfaces exhibit reduced superheat requirements and enhanced boiling heat transfer coefficients for equivalent heat flux densities. Furthermore, the rewetting characteristics of hybrid wettability surfaces are identified as pivotal factors in determining their critical heat flux (CHF). This investigation underscores the potential of hybrid wettability surfaces to optimize pool boiling heat transfer, offering valuable insights for the design and en-hancement of heat exchangers and other thermal management systems.