Diagenesis and pore structure are essential factors for reservoir evaluation. marine-continental transitional facies shale is a new shale gas reservoir of concern in the Sichuan Basin. The research on its diagenesis pore evolution model has important guiding significance in its later exploration and development. However, the current research on pore structure changes, diagenesis, and the evolution of marine-continental transitional facies shale is not sufficient and systematic. In order to reveal the internal relationship between pore structure changes and diagenesis, the evolution of marine-continental transitional facies shale was tested by X-ray diffraction, field emission scanning electron microscopy, low-pressure gas adsorption, nuclear magnetic resonance, and the diagenetic evolution sequence and nanopore system evolution of Longtan Formation shale was systematically studied. The results show that the Longtan Formation shale underwent short-term shallow after sedimentation, followed by long-term deep burial. The main diagenetic mechanisms of the Longtan Formation shale include compaction, dissolution, cementation, thermal maturation of organic matter, and transformation of clay minerals, which are generally in the middle-late diagenetic stage. The pore structure undergoes significant changes with increasing maturity, with the pore volumes of both micropores and mesopores reaching their minimum values at Ro = 1.43% and subsequently increasing. The change process of a specific surface area is similar to that of pore volumes. Finally, the diagenetic pore evolution model of Longtan Formation MCFS in Southeastern Sichuan was established.

The temperature changes in the middle-late Eocene had a profound impact on various ecosystems around the world. This has been confirmed not only in marine sediments but also in lake ecosystems, which have provided more detailed isochronous continental sedimentary records. Based on systematic palynological and element analyses of fine-grained lacustrine sediments from the Xijiang main subsag in the Pearl River Mouth Basin, southern China, we reconstructed the climate evolution of the middle-late Eocene. A total of 73 genera and 115 species of sporopollen fossils were identified from the middle-late Eocene in the study area. Three pollen zones comprising Quercoidites–Polypodiaceaesporites–Pinuspollenites, Pinuspollenites–Ulmipollenites–Cedripites, and Pinuspollenites–Abietineaepollenites–Juglanspollenites were established from bottom to top. The analysis of the vegetation types, climatic zones, and dry–humid types of the sporopollen showed that, in the study area, the Eocene was dominated by a subtropical–warm temperate climate: the early-late Eocene was dominated by a temperate climate, and the late Eocene was characterized by the prevalence of a warm temperate climate, which was consistent with the palaeoclimate reconstruction results for element geochemical indices (Fe/Mn, Sr/Cu, CIA, PIA, etc.). In addition, the comparative study showed that the middle-late Eocene in the study area was characterized by a warm and humid climate, which transitioned to a warm and cool semihumid–semiarid climate and then a warm and cool semihumid climate. These findings demonstrated a good coupling relationship with the trend for the changes in the global palaeotemperature and can be used as an isochronous continental sedimentary response.

This study aims to explore the reservoir characteristics and formation mechanisms of ultra-deep shale gas in the Ordovician–Silurian Wufeng–Longmaxi Formation in the Sichuan Basin in order to provide theoretical support and practical guidance for the exploration and development of ultra-deep shale gas. With recent breakthroughs in ultra-deep shale gas exploration, understanding its organic matter development, mineral composition, and reservoir space characteristics has become particularly important. The background of this research lies in the significant potential of ultra-deep shale gas, which remains inadequately understood, necessitating an in-depth analysis of its pore structure and reservoir quality. Through a systematic study of the ultra-deep shale in well FS1 of Sichuan Basin, that the following was found: (i) The ultra-deep shale in the Wufeng–Longmaxi Formation is mainly composed of quartz and clay minerals, exhibiting high total organic carbon (TOC) and high porosity characteristics, indicating it is in an overmature thermal evolution stage. (ii) Organic pores and microcracks in the ultra-deep shale are more developed compared to middle-shallow and deep shale, forming a complex pore structure that is conducive to gas storage. (iii) In the diagenesis process, the dissolution and recrystallization of the biogenic skeleton promote the cementation between autogenetic quartz particles, forming a rigid skeleton that effectively inhibits the impact of mechanical compaction. (iv) The overpressure environment created by the hydrocarbon generation process, along with gas production from hydrocarbon cracking, can effectively offset the mechanical compaction of overburden pressure on micropores, and this overpressure environment also promotes the further development of microfractures, which is beneficial for the development and preservation of ultra-deep shale pores. In summary, this study not only reveals the reservoir characteristics and formation mechanisms of ultra-deep shale but also provides essential references for the exploration and development of ultra-deep shale gas in the Sichuan Basin and similar regions, emphasizing the ongoing significance of research in this field.