Per- and polyfluoroalkyl substances (PFAS) are persistent and bioaccumulative pollutants that can easily accumulate in soil, posing a threat to environment and human health. Current PFAS degradation processes often suffer from low efficiency, high energy and water consumption, or lack of generality. Here, we develop a rapid electrothermal mineralization (REM) process to remediate PFAS-contaminated soil. With environmentally compatible biochar as the conductive additive, the soil temperature increases to >1000 °C within seconds by current pulse input, converting PFAS to calcium fluoride with inherent calcium compounds in soil. This process is applicable for remediating various PFAS contaminants in soil, with high removal efficiencies ( >99%) and mineralization ratios ( >90%). While retaining soil particle size, composition, water infiltration rate, and cation exchange capacity, REM facilitates an increase of exchangeable nutrient supply and arthropod survival in soil, rendering it superior to the time-consuming calcination approach that severely degrades soil properties. REM is scaled up to remediate soil at two kilograms per batch and promising for large-scale, on-site soil remediation. Life-cycle assessment and techno-economic analysis demonstrate REM as an environmentally friendly and economic process, with a significant reduction of energy consumption, greenhouse gas emission, water consumption, and operation cost, when compared to existing soil remediation practices.

This review explores the tribological properties of biosourced lubricants (biolubricants) enhanced by graphene (Gr) and its derivatives and hybrids. Friction and wear at mechanical interfaces are the primary causes of energy loss and machinery degradation, necessitating effective lubrication strategies. Traditional lubricants derived from mineral oils present environmental challenges, leading to an increased interest in biolubricants derived from plant oils and animal fats. Biolubricants offer high biodegradability, renewability, and low toxicity, positioning them as ecofriendly alternatives. This work extensively reviews the role of Gr-based nanoadditives in enhancing the lubrication properties of biolubricants. Gr with its exceptional physicomechanical properties has shown promise in reducing friction and wear. The review covers various Gr derivatives, including Gr oxide (GO) and reduced Gr oxide (r-GO), and their performance as lubrication additives. The discussion extends to Gr hybrids with metals, polymers, and other 2D materials, highlighting their synergistic effects on the tribological performance. The mechanisms through which these additives enhance lubrication, such as the formation of protective films and improved interactions between lubricants and tribopairs, are examined. Emphasis is placed on the environmental benefits and potential performance improvements of Gr-based biolubricants. Finally, by analyzing current research and technological trends, the paper outlines future prospects for optimizing lubricant formulations with Gr-based nanoadditives, aiming for more sustainable and efficient tribological applications.

Water contamination with "forever chemicals" like per- and polyfluoroalkyl substances (PFAS) poses significant toxicity to the environment. Since they are the most persistent synthetic chemicals that hardly degrade in the natural environment and are carcinogenic to humans, there is an urgent need to discover novel processes for destroying PFAS. Herein, we report on the design of a reduced graphene oxide (r-GO)/WO₃ nanoflower (WO₃-NF)-based heterostructure for harnessing 365 nm light-driven photocatalytic oxidation and reduction process toward the photocatalytic degradation of perfluorononanoic acid (PFNA). Moreover, reported data reveal that using an r-GO/WO₃-NF heterostructure photocatalyst, 100% PFNA degradation and 14% defluorination can be achieved in the presence of isopropyl alcohol as the hydroxy radical (^•OH) quencher or glucose as a hot hole (h⁺) quencher after exposure to 365 nm light for 22 h. A reported mechanistic study shows synergistic oxidation and reduction processes are vital for the complete degradation of PFNA, where the hydrated electron (e_aq ^-) plays a key role as a reducing agent and h⁺ and ^•OH act as oxidation agents. Furthermore, the photocatalytic destruction mechanism study indicates that chain shortening via C-C bond breaking and defluorination via C-F bond breaking are major pathways for PFNA degradation. A wavelength-dependent study shows that only 22% degradation can be achieved after exposure to 532 nm light for 22 h, which is due to the lack of the formation of hydrated electrons (e_aq ^-). The current study sheds light on the construction of the r-GO/WO₃ NF heterojunction for the highly efficient degradation of PFAS.

The contamination of drinking water by per- and polyfluoroalkyl substances (PFASs) presents a global concern due to their extreme persistence, driven by strong C–F bonds. This study investigated the potential of graphene as a filtration material for PFAS removal, focusing on six key compounds regulated by the U.S. EPA: PFOA, PFNA, GenX, PFBS, PFOS, and PFHxS. Using molecular simulations, adsorption energy, diffusion coefficients, and PFAS-to-graphene distances were analyzed. The results showed that adsorption strength increased with molecular weight; PFOS (500 g/mol) exhibited the strongest adsorption (−171 kcal/mol). Compounds with sulfonic acid head groups (e.g., PFOS) had stronger interactions than those with carboxylate groups (e.g., PFNA), highlighting the importance of head group chemistry. Shorter graphene-to-PFAS distances also aligned with higher adsorption energies. PFOS, for example, had the shortest distance at 8.23 Å (head) and 6.15 Å (tail) from graphene. Diffusion coefficients decreased with increasing molecular weight and carbon chain length, with lower molecules like PFBS (four carbon atoms) diffusing more rapidly than heavier ones like PFOS and PFNA. Interestingly, graphene enhanced PFAS mobility in water, likely by disrupting the water structure and lowering intermolecular resistance. These results highlight graphene’s promise as a high-performance material for PFAS removal and future water purification technologies.

Green synthesis plays a crucial role in advancing sustainability within materials science. This study explores the integration of metal–organic frameworks (MOFs), obtained through green synthesis, using an electrospinning post-processing technique to develop MOF-based composite materials. The resulting novel multifunctional composites demonstrate enhanced stability and functionality, compared to their control counterparts. The integration of four types of MOFs into an electrospun fiber network was investigated using a specific polymer solution. Characterization and preliminary adsorption studies were conducted to elucidate the chemistry, morphology, and adsorptive capabilities of the resulting MOF composites. Electrospinning MOFs into polymer fibers improved their stability and dye removal capabilities. More specifically, optimization of MOF-to-polymer ratios and processing conditions yielded composites that are thermally stable, with modified surface area and porosity. Post-processing MOFs resulted in a fiber diameter increase of 44 and 109%, enhancing the composites by providing more MOF active sites and improved mechanical strength. Zirconium-based post-processed MOFs demonstrated superior dye removal, different from the copper-based dyes. Electrospinning technology has demonstrated significant potential in the fabrication of high-performance multifunctional MOF composites. This has helped to create advanced sustainable composites with tailored properties, paving the way for more targeted and efficient applications. The applications of these composites show promise for military engineering where durable, light weight, and multifunctional materials are critical in contributing to improved performance, operational efficiency, and safety.