An integrated soda roasting–alkaline leaching–carbonization process was developed to recover platinum (Pt) and aluminum (Al) from a spent Pt/Al2O3 catalyst. A product with the main component of NaAlO2 was obtained under the optimal roasting conditions of the mass ratio of Na2CO3 to spent catalyst 1, roasting time 2 h and roasting temperature 900 °C. The Al in the roasted residue was effectively leached in a dilute NaOH solution, while Pt was enriched in the leached residue with a Pt content that reached 29.4%, and the calculated concentration factor of Pt yielded 79.4. After carbonization was performed for the leached solution, 99.0% of the Al was recovered as the pseudo-boehmite product, which could be used as the feed for preparing the Al2O3 carrier. Pt and Al2O3 in the spent catalyst were selectively separated and enriched using the above process, which thus has good application prospects.
25 January 2019 in Metallurgical Research & Technology
A roast-leach process has been developed for concentrating platinum (Pt) from a spent Pt-Al2O3 catalyst. The effects of (NH4)2SO4 to spent catalyst mass ratio, roasting temperature and roasting time on the Pt enrichment factors were investigated. The results showed that the optimized roasting conditions were (NH4)2SO4 to spent catalyst mass ratio of 7.5, roasting temperature of 350 °C and roasting time of 5 h. The roasted product was mainly comprised of soluble NH4Al(SO4)2 and Al2(SO4)3 according to XRD analysis. The roasted product was leached in sulfuric acid to remove the soluble sulfates, and meanwhile Pt was kept in the residue. Under optimized conditions, a Pt concentrate with Pt content of 73.2% could be obtained from the spent catalyst with 0.27% Pt, and the corresponding Pt enrichment factor was more than 270.
DNA and RNA simultaneously extracted from A. f using the optimised method. (a) Total nucleic acid extracted from A. f : lane M1, 1 kb ladder; lane M2, Hind III-cut lambda molecular size marker; lanes 1–4, biological replicates. (b) DNA precipitated by isopropanol. (c) RNA precipitated by LiCl.