A three-dimensional helix geometry unit cell is established to simulate the complex spatial configuration of 3D braided composites. Initially, different types of yarn factors, such as yarn path, cross-sectional shape, properties, and braid direction, are explained. Then, the multiphase finite element method is used to develop a new theoretical calculation procedure based on the unit cell for predicting the impacts of environmental temperature on the thermophysical properties of 3D four-direction carbon/epoxy braided composites. The changing rule and distribution characteristics of the thermophysical properties for 3D four-direction carbon/epoxy braided composites are obtained at temperatures ranging from room temperature to 200 °C. The influences of environmental temperature on the coefficients of thermal expansion (CTE) and the coefficients of thermal conduction (CTC) are evaluated, by which some important conclusions are drawn. A comparison is conducted between theoretical and experimental results, revealing that variations in temperature exert a notable influence on the thermophysical characteristics of 3D four-directional carbon/epoxy braided composites. The theoretical calculation procedure is an effective tool for the mechanical property analysis of composite materials with complex geometries.

Magnesium sulphoaluminate (MSA) cement has good bonding properties and is suitable as an inorganic adhesive for repairing materials in civil engineering. However, there are still some problems with its use, such as its insufficient 1 day (d) strength and poor volumetric stability. This paper aims to investigate the influences of metakaolin (MK) on the physical and mechanical properties of magnesium sulphoaluminate (MSA) cement. The hydration products and microstructures of typical MSA cement samples were also analysed using X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDS). The results showed that the addition of metakaolin reduces the fluidity and shortens the setting time of the MSA cement. The initial setting time and final setting time shortened maximally by 15–27 min and 25–48 min, respectively, with the addition of 10–30% metakaolin. Moreover, the compressive strength and flexural strength of the MSA cement improved significantly with the addition of 10–30% metakaolin at a curing age of 1 d. Compared with the compressive and flexural strengths of the control sample at 1 d, the compressive strengths of the modified samples showed obvious increases of 98%, 101%, and 109%, and the flexural strengths increased by 39%, 31%, and 26%, respectively, although they decreased slightly when the curing ages were 7 d, 14 d, and 28 d. The addition of 10% metakaolin improved the water resistance of the MSA cement immersed in water for 7 d and resulted in even higher water resistance at 28 d. The addition of 10–30% metakaolin improved the volumetric stability of the MSA cement with increasing dosages before 28 d of ageing. XRD and SEM-EDS analyses showed that the metakaolin accelerated the early hydration reaction and optimised the phase composition of the MSA cement. The results indicate that the addition of 10–20% metakaolin improved the strength after 1 d of ageing, water resistance, and volumetric stability of the MSA cement, providing theoretical support for the application of MAS cement as an inorganic bonding agent for repairing materials.

To improve the construction performance of inorganic adhesives used for bonding fiber-reinforced polymer (FRP) sheets to reinforce concrete structures, make rational use of resources, and reduce carbon emissions, double-shear tests on the interface bonding performance between bonded FRP sheets and cement mortar test blocks, as well as four-point bending tests on bonded carbon fiber-reinforced polymers (CFRPs) to reinforce concrete beams, were conducted using basic magnesium sulfate cement (BMSC) as the adhesive. The influence laws of parameters, such as the type of FRP sheet and the number of FRP sheet bonding layers on the shear performance of the bonding interface between BMSC and cement mortar test blocks, were investigated, as well as the influence laws of the number of CFRP sheet bonding layers and the type of binder on the bending performance of CFRP sheet-reinforced beams. The test results show that the ultimate load of CFRP-reinforced beams bonded with BMSC as the binder increased by 17.4% to 44.4% compared with the unreinforced beams and simultaneously improved the flexural stiffness and crack-limiting ability of the reinforced beams. The failure of the reinforced beam begins with the separation of the CFRP sheet from the concrete at the middle and bottom of the beam span. When the CFRP sheet of the reinforced beam is one layer and two layers, the flexural bearing capacity reaches 91.4% and 96%, respectively, of the reinforced beam, with epoxy resin as the binder under the same conditions. With the increase in the number of CFRP layers, the flexural bearing capacity of the reinforced beam improves, but the increased flexural bearing capacity does not increase proportionally with the increase in the number of sheet layers. By introducing the influence coefficient of BMSC on the flexural bearing capacity (FBC) of reinforced beams, based on the test results, the formula for calculating the FBC of concrete beams, which are reinforced with CFRP sheets bonded by BMSC, was developed. After verification, the calculation formulas established in this paper have high accuracy and can provide theoretical references for similar engineering applications.