Two-dimensional (2D) layered semiconductors are a novel class of functional materials that are an ideal platform for electronic applications, where the whole electronic states are directly modified by external stimuli adjacent to their electronic channels. Scale-up of the areal coverage while maintaining homogeneous single crystals has been the relevant challenge. We demonstrate that wafer-size single crystals composed of an organic semiconductor bimolecular layer with an excellent mobility of 10 cm² V⁻¹ s⁻¹ can be successfully formed via a simple one-shot solution process. The well-controlled process to achieve organic single crystals composed of minimum molecular units realizes unprecedented low contact resistance and results in high-speed transistor operation of 20 MHz, which is twice as high as the common frequency used in near-field wireless communication. The capability of the solution process for scale-up coverage of high-mobility organic semiconductors opens up the way for novel 2D nanomaterials to realize products with large-scale integrated circuits on film-based devices.

High-mobility organic transistors are fabricated on both surfaces of approximately 1-μm-thick rubrene crystals, molecularly flat over an area of 10×10μm2. A thin platelet of 9,10-diphenylanthracene single crystal and surface-passivated SiO2 are used for the gate insulators. Because of the minimized densities of hole-trapping levels at the interfaces and in the rubrene crystal, the field-induced carriers do not necessarily reside near the interface but are distributed in the bulk of the semiconductor by adjusting the two gate voltages. Making use of the highly mobile carriers in the inner crystal, the mobility is maximized to ∼43cm2∕Vs.

We have demonstrated for the first time the feasibility of using a rewritable dual-layer phase-change optical disk utilizing a blue-violet laser. For the first medium, we adopted a very thin recording layer with a new phase-change material Ge–Sn–Sb–Te, and a 10-nm-thick silver-alloy reflective layer to obtain a large transmittance and high-quality signals. For the second medium, we optimized the thickness of each layer to obtain both a large optical absorption of the recording layer and a small heat capacity. Carrier-to-noise ratios of more than 50 dB, erasability of more than 30 dB and recording powers of 8 mW for the first medium and 11 mW for the second medium were obtained under typical recording conditions corresponding to a capacity of 27 GB per one side of a 120 mm disk and a user data transfer rate of 33 Mbps.