Karstic aquifers are well known for their vulnerability to groundwater contamination. This is due to characteristics such as thin soils and point recharge in dolines, shafts, and swallow holes. In karstic areas, groundwater is often the only freshwater source. This is the case of the Apulia region (south-eastern Italy), where a large and deep carbonate aquifer, affected by karstic and fracturing phenomena, is located. Several methods (GOD, DRASTIC, SINTACS, EPIK, PI, and COP) for the assessment of the intrinsic vulnerability (Iv) were selected and applied to an Apulian test site, for which a complete data set was set up. The intrinsic vulnerability maps, produced using a GIS approach, show vulnerability from low to very high. The maximum vulnerability is always due to karstic features. A comparison approach of the maps is proposed. The advantages and disadvantages of each method are discussed. In general terms, three groups can be distinguished. The GOD method is useful for mapping large areas with high vulnerability contrasts. DRASTIC and SINTACS are "any-type aquifer" methods that have some limitations in applications to karstic aquifers, especially in the case of DRASTIC. EPIK, PI, and COP, which were designed to be applied to carbonate or karstic aquifers, supply affordable results, highly coherent with karstic and hydrogeological features, and reliable procedures, especially in the case of PI and COP. The latter appears simpler to apply and more flexible in considering the role of climatic parameters. If Iv of each method is considered, the highest variability is observed in cells in the neighbourhood of karstic features. In these spatial domains, additional efforts to define more reliable and global methods are required.

The Cesine Wetland, located along the Adriatic coast, was recognized as a Wetland of International Interest and a National Natural Park. Managed by the “World Wide Fund for nature” (WWF), it is considered a groundwater dependent ecosystem which is affected by seawater intrusion. The site was selected to test the environmental compatibility of a low-enthalpy geothermal power plant (closed loop) operating in the aquifer saturated portion with purpose to improving the visitor centre. For this purpose, the long-lasting thermal impact on groundwater was assessed using a multi-methodological approach. The complex aquifer system was carefully studied with geological, hydrogeological and geochemical surveys, including chemical and isotopic laboratory analyses of surface water, groundwater and seawater. The isotopes δ¹⁸O, δD, δ¹¹B, and ³H were useful to clarify the recharge contribution, the water mixing and the water age. All information was used to improve the conceptualization of the water system, including aquifers and the boundary conditions for a density driven numerical groundwater model. The purpose was to forecast anthropogenic thermal groundwater variations up to 10 years of plant working before the plant realization and to validate the solution after some working years. All results show the environmental compatibility notwithstanding the peculiar ecological environment.

Landfill sites are subjected to long-term risks of accidental spill of leachate through the soil and consequential contamination of the groundwater. Wide areas surrounding the landfill can seriously be threatened with possible consequences to human health and the environment. Given the potential impact of different coexisting anthropic pollution sources (i.e., agriculture and cattle farming) on the same site, the perturbation of the groundwater quality may be due to multiple factors. Therefore, it is a challenging issue to correctly establish the pollution source of an aquifer where the landfill is not isolated from other anthropic land uses, especially in the case of a karstic coastal aquifer. The present study is aimed at setting in place an integrated environmental monitoring system that included microbiological, chemical, and isotope methods to evaluate potential groundwater pollution in a landfill district in the south of Italy located in Murgia karstic aquifer. Conventional (microbial plate count and physical–chemical analyses) and advanced methods (PCR-ARISA, isotope analysis of δ¹⁸O, δ²H, ³H, δ ¹³C, δ ¹⁵N-NO₃⁻, and δ ¹⁸O-NO₃⁻) were included in the study. Through data integration, it was possible to reconstruct a scenario in which agriculture and other human activities along with seawater intrusion in the karst aquifer were the main drivers of groundwater pollution at the monitored site. The microbiological, chemical, and isotope results confirmed the absence of leachate effects on groundwater quality, showing the decisive role of fertilizers as potential nitrate sources. The next goal will be to extend long-term integrated monitoring to other landfill districts, with different geological and hydrogeological characteristics and including different sources of pollution, to support the ecological restoration of landfills.

The study discusses the large karstic coastal aquifer of Vlora Bay. This case is peculiar, as the submarine groundwater discharge has a relevant rate of terrestrial inflow in an almost closed bay that is located in an environmentally valuable area. The study is based on four methodological activities: geological and hydrogeological conceptualisation, climatic study and hydrological balance, numerical modelling, and monitoring. A geodatabase was created considering hundreds of data points (wells, springs, rivers, lagoons, and seas) and monthly time series of rainfall, temperature, and river discharge. Monitoring activity was realised over a hydrological year, installing a rainfall network tool and using a network of tens of sampling points, including springs, wells, lagoons and sea. Chemical-physical and stable isotope determinations were realised. Two main groups of aerial springs are fed by the aquifer, one of which is of a coastal type. The total spring discharge is roughly 4 m3/s. The GSD was assessed as being equal to 1.4 m3/s on the basis of the current rate of anthropic discharge and climatic conditions. The study showed the peculiarities of this carbonate coastal aquifer and the importance of its groundwater, which is the chief water source for the third-largest Albanian town. The groundwater quality was generally high, mainly due to the negligible presence of contamination sources on the relief in which the aquifer outcrops. The rate of seawater intrusion effects was also low, thanks to favourable aquifer 3-D geometry and high recharge levels. The increasing anthropic activities constitute a relevant risk in the absence of the introduction of rigorous land and water management criteria