The complex dielectric permittivity of aqueous solutions of tetrahydrofuran and dimethylformamide in wide ranges of temperature (220–300 K) and pressure (0.1–12 MPa) is studied by means of molecular d

(1) Background: Currently, nanomaterials have been broadly used in various applications including engineering, medicine and biology. One of the carbon allotropes such as carbon nanotubes (CNTs) implemented for fabrication of nanocomposite materials due to the hypersensitivity. The combined design of nanomaterial with chitosan (CS) and CNT expands the field of exploitation from biosensing and tissue engineering to water desalination. Therefore, the penetration of CS into CNT provides a valuable insight into the interactions between CS and CNT. (2) Methods: We performed molecular dynamics simulations, applying the umbrella sampling method, in order to calculate the potential mean force between CS and CNT. (3) Results: The estimated penetration free energies showed that CS is favorable to the penetration into CNT cavities. However, the penetration nature differs depending on the CNT’s architecture. (4) Conclusions: Our finding revealed the CS penetration process into CNT with nanoscale precision. The investigation results assist in a better understanding of the nanocomposite materials based on CS-CNT.

This work presents the fabrication of a coaxial fiber triboelectric sensor (CFTES) designed for efficient energy harvesting and gesture detection in wearable electronics. The CFTES was fabricated using a facile one-step wet-spinning approach, with PVDF-HFP/CNTs/Carbon black as the conductive electrode and PVDF-HFP/MoS₂ as the triboelectric layer. The incorporation of 1T phase MoS₂ into the PVDF-HFP matrix significantly improves the sensor’s output owing to its electron capture capabilities. The sensor’s performance was carefully optimized by varying the weight percentage of MoS₂, the thickness of the fiber core, and the CNT ratio. The optimized CFTES, with a core thickness of 156 µm and 0.6 wt% MoS₂, achieved a stable output voltage of ~8.2 V at a frequency of 4 Hz and 10 N applied force, exhibiting remarkable robustness over 3600 s. Furthermore, the CFTES effectively detects human finger gestures, with machine learning algorithms further enhancing its accuracy. This innovative sensor offers a sustainable solution for energy transformation and has promising applications in smart portable power sources and wearable electronic devices.

The problems of processing spent adsorbents with a high concentration of chemisorbed chlorine-containing compounds for their reuse are studied in this article. The genesis of the phase composition and morphology at all technological stages of thermochemical regeneration of the spent adsorbent - Axstrap-860 by means of alkaline modification with a combined solution of sodium and potassium hydroxides has been tested by diffractometry and elemental analysis. The results show that the formation of a layer with an increased concentration of alkali metals in the form of the corresponding carbonates and NaOH on the surface of the granules and in the volume of sodium and potassium aluminates provides adsorption of HCl, which are slightly inferior to the fresh adsorbent. The conditions for the removal of halogen-containing substances from technogenic raw materials with the subsequent isolation of useful products have been optimized: (1) crystalline NaCl intended for the preparation of electrolyte for electrode boilers and steam generators; (2) a mixture of chlorides and hydroxochlorides of aluminum tested in the process of coagulation purification of turbid natural and waste waters; (3) pseudoboehmite for the production of an adsorbent-desiccant and the synthesis of magnesium-aluminum spinel using the technology of destruction-epitaxial transformation, and a promising carrier for catalysts for steam reforming of hydrocarbons. Copyright © 2021 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).

In this study, we modified Ni based electrodes with MXene and MXene-based composite catalysts for water splitting. The MXene based catalyst exhibited excellent electrochemical surface area (ECSA) of 1840 cm ² , highlighting its abundant active sites. To further enhance catalytic activity, MXene was modified with graphene oxide (GO) and carbon black (CB), which significantly reduced the overpotential from 300 mV to 196 mV at 10 mA cm ⁻² and improved the reaction kinetics, as evidenced by a low Tafel slope of 96.35 mV dec ⁻¹ . Moreover, the MXene–GO–CB composite demonstrated outstanding long-term durability, maintaining stable operation for 50 h at 100 mA cm ⁻² with only a 34 mV increase in overpotential at 10 mA cm ⁻² . These results confirm that the synergistic combination of MXene with GO and CB yields a highly active and durable electrocatalyst, offering strong potential for practical water electrolysis applications.