In the paper spent coffee grounds were used as a precursor to obtain activated carbons. The raw material was impregnated with phosphoric acid(V) at the different impregnations ratios: 0.5, 1, 1.5, 2. Carbonization was carried out according to two procedures differing in activation atmosphere (N₂ or CO₂). The obtained activated carbons were characterized on the basis of low-temperature nitrogen adsorption/desorption, thermal analysis, potentiometric titration method, X-ray diffraction, Raman spectroscopy and scanning electron microscopy. Carbons obtained according to procedure 2 (activation in CO₂) were characterized by better developed porosity, e.g. surface (S_BET to 720.9 m²/g) and pore volume (V_p to 0.334 cm³/g). All obtained carbons had surface acidic (mainly carboxyl) groups and exhibited the amorphous structure. The thermal analysis showed that the obtained materials were thermally stable up to the temperature ~ 420 °C.

In this study four kinds of biochars were prepared from the KOH modified biomass. As the carbon precursors there was used the sawdust from the following trees: oak, hornbeam, apple and cherry. The physicochemical properties of the materials were characterized by the N₂ adsorption, scanning electron microscopy, thermal analysis (TG, DTG and DTA), infrared spectroscopy, and the Boehm’s titration method. Moreover, pH_pzc (the point of zero charge) was determined. The adsorption capacity and the temperature-programmed desorption of ammonia were also studied. The obtained activated biochars were characterized by the large specific surface area (672 to 912 m²/g) and the total pore volume (0.30 to 0.4 cm³/g) as well as the well-developed microporous structure (85–97%). These observations were also confirmed by the SEM analysis. The maximum NH₃ adsorption capacity of the activated biochar was determined to be 3.05 mmol/g. These results prove that the sawdust of various origins is appropriate to prepare a cost-effective, environmentally friendly biochar.

The adsorption of paracetamol and non-steroidal anti-inflammatory drugs (ibuprofen and naproxen) on ordered mesoporous carbons (OMC) and, for comparison, on commercial activated carbon, were investigated in this work. OMC adsorbents were obtained by the soft-templating method and were characterized by low-temperature nitrogen adsorption and scanning electron microscopy (SEM). The effects of contact time and initial concentration of organic adsorbates on the adsorption were studied. The contact time to reach equilibrium for maximum adsorption was 360 min for all the studied adsorbates. The adsorption mechanism was found to fit pseudo-second-order and intra particle-diffusion models. Freundlich, Langmuir and Langmuir-Freundlich isotherm models were used to analyze equilibrium adsorption data. Based on the obtained experimental data, the adsorption isotherm in the applied concentration range for all the studied adsorbates was well represented by the Freundlich-Langmuir model. The adsorption ability of ordered mesoporous carbon materials was much higher for paracetamol and naproxen in comparison to commercial activated carbon. The removal efficiency for ibuprofen was significantly lower than for other studied pharmaceuticals and comparable for all adsorbents. Theoretical calculations made it possible to obtain optimized chemical structures of (S)-naproxen, ibuprofen, and paracetamol molecules. Knowledge of charge distributions of these adsorbate molecules can be helpful to explain why paracetamol and naproxen can react more strongly with the surface of adsorbents with a large numbers of acidic groups compared to ibuprofen facilitating more efficient adsorption of these pharmaceuticals on ordered mesoporous carbons.

In the presented research, activated carbons from wheat bran were obtained as a result of pyrolysis and physical activation (CO₂ or/and steam). In addition, the obtained materials were subjected to additional modification with superheated steam using the microwave radiation as an energy source. The detailed materials characterization was performed using low-temperature nitrogen adsorption/desorption, Raman spectroscopy, X-ray diffraction, thermal analysis (TG), Boehm’s titration, point of zero charge (pH_pzc), scanning electron microscopy (SEM) and FT-IR/ATR methods. Moreover, the sorption capacity towards methylene blue (MB) was determined. The activated carbons were characterized with a well-developed surface and pore structure (S_BET = 339.6–594.0 m²/g; V_p = 0.157–0.356 cm³/g). Activation in the presence of steam and additional modification with microwave radiation resulted in much better development of the porous structure (S_BET = 600.4 m²/g; V_p = 0.380 cm³/g). The materials were shown to possess amorphous structure and thermal stability up to the temperatures of ~450–500 °C. They have good adsorption capacity towards MB varying from 150 mg/g to 241 mg/g depending on activation manner. The adsorption can be described by the pseudo-second order model (R² = 0.99) and fitted to the Langmuir isotherm.

In this work, adsorption of rhodamine B (RB) and acid yellow 17 (AY17) was investigated on ordered mesoporous carbon material obtained by soft-templating method with hydrochloric acid (ST-A). For comparison, the adsorption process on commercial activated carbon CWZ-22 was also carried out. The sorbents were characterized by nitrogen adsorption/desorption isotherms and scanning electron microscopy. Langmuir and Freundlich adsorption isotherm models were applied to simulate the equilibrium data of RB and AY17. Adsorption isotherm data could be better described by the Langmuir model than the Freundlich model. The adsorption kinetics of RB and AY17 on studied carbons could be well depicted by using pseudo-second-order kinetic modeling. The adsorption capacity increased with temperature increase in the range of 298–315 K. In the whole diffusion process, the intraparticle diffusion was involved, but not the whole rate-controlling step. The calculated thermodynamic parameters, including Gibbs free energy (∆G), enthalpy (∆H), and entropy (ΔS) suggested that adsorption processes of RB and AY17 on ST-A and CWZ-22 were endothermic and spontaneous.

In this study the pyrolysis of Norway spruce cones, a lignocellulosic biomass was made. The biochar product was obtained by means of the physical activation method. CO₂ was used as the activating gas. The surface properties of biochars were characterized by the nitrogen adsorption/desorption isotherms, scanning electron microscopy (SEM/EDS), X-ray fluorescence energy dispersion spectroscopy (ED-XRF), thermal analysis (TGA/DTA), infrared spectroscopy (ATR FT-IR), Raman spectroscopy and the Boehm’s titration method as well as the point of zero charge (pH_pzc). The adsorption capacity and the possibility of ammonia desorption (TPD) were also examined. It has been shown that spruce cones can be successfully used as a cheap precursor of well-developed surface biochars, characterized by a large pore volume and good sorption properties. All obtained activated biochars exhibit a largely microporous structure and an acidic character surface. The investigated activated materials have the specific surface areas from 112 to 1181 m² g⁻¹. The maximum NH₃ adsorption capacity of the activated biochar was determined to be 5.18 mg g⁻¹ (88.22 mmol g⁻¹) at 0 °C. These results indicate the applicability of spruce cones as a cheap precursor for the sustainable production of the cost-effective and environmentally friendly biochar adsorbent.