This study develops a new concept involving using the existing infrastructure for photovoltaic (PV) generation to reduce the costs associated with increased land use and to avoid curtailment due to the mismatch between power supply and demand. We establish a method to estimate the technological potential and economic performance of the PV systems deployed in coal-fired power plants in China. The potential capacity of the examined 1,082 units in China reaches 4 GWe, which is equivalent to 32% of China's newly installed distributed PV capacity in 2019. A total of 87% of PV systems achieve plant-side grid parity compared with desulfurized coal benchmark electricity prices. To the best of our knowledge, this is the first study that investigates the use of rooftops and coal storage sheds in power plants to facilitate low-cost, flexible PV power generation, thus opening a new channel for future PV generation development.

The expansively unutilized rooftop spaces in the university campuses can provide an excellent opportunity for the installation of solar photovoltaic systems to achieve renewable electricity generation and carbon dioxide reduction. Based on available rooftop areas and local solar radiation situations, technical potential and economic benefits of rooftop photovoltaic system under seven scenarios were carried out for three university campuses located in different solar zones in China. The potential capacity of photovoltaic installations on building’s flat rooftops in Tibet University, Qinghai University, and Qilu University of Technology reaches 11,291 kW, 9102 kW, and 3821 kW, corresponding to the maximum annual power generation of 28.19 GWh, 18.03 GWh, and 5.36 GWh, respectively. From the perspective of economic analysis, PV systems installed in “full self-consumption” mode are superior to those installed in “full-feed-into-grid” mode for all three study cases. The highest return on investment of PV systems installed on flat and pitched rooftops can be achieved at 208% and 204%, respectively, in Tibet University. The payback period for PV systems installed on flat rooftops is 1 year in Tibet University, and less than 8 years for both Qinghai University and Qilu University of Technology, respectively. Results reveal that rooftop photovoltaic systems can significantly help the universities to move towards sustainability.

Developing an OER electrocatalyst that balances high performance with low cost is crucial for widely adopting PEM water electrolyzers. Ru-based catalysts are gaining attention for their cost-effectiveness and high activity, positioning them as promising alternatives to Ir-based catalysts. However, Ru-based catalysts can be prone to oxidation at high potentials, compromising their durability. In this study, we utilize a simple synthesis method to synthesize a SnO₂, Nb₂O₅, and RuO₂ composite catalyst (SnO₂/Nb₂O₅@RuO₂) with multiple interfaces and abundant oxygen vacancies. The large surface area and numerous active sites of the SnO₂/Nb₂O₅@RuO₂ catalyst lead to outstanding acidic oxygen evolution reaction (OER) performance, achieving current densities of 10, 50, and 200 mA cm⁻² at ultralow overpotentials of 287, 359, and 534 mV, respectively, significantly surpassing commercial IrO₂. Moreover, incorporating Nb₂O₅ into the SnO₂/Nb₂O₅@RuO₂ alters the electronic structure at the interfaces and generates a high density of oxygen vacancies, markedly enhancing durability. Consequently, the membrane electrode composed of SnO₂/Nb₂O₅@RuO₂ and commercial Pt/C demonstrated stable operation in the PEM cell for 25 days at an industrial current density of 1 A cm⁻². This research presents a convenient approach for developing a highly efficient and durable Ru-based electrocatalyst, underscoring its potential for proton exchange membrane water electrolysis.