Presumed source specificity of branched glycerol dialkyl glycerol tetraethers (brGDGTs) from bacteria thriving in soil/peat and isoprenoid GDGTs (iGDGTs) from aquatic organisms led to the development of several biomarker proxies for biogeochemical cycle and paleoenvironmental reconstructions. However, recent studies reveal that brGDGTs are also produced in aquatic environments besides soils and peat. Here we examined three cores from the Bohai Sea, and found distinct difference in brGDGT compositions varying with the distance from the Yellow River mouth. We thus propose an abundance ratio of hexamethylated to pentamethylated brGDGT (IIIa ∕ IIa) to evaluate brGDGT sources. The compilation of globally distributed 1354 marine sediments and 589 soils shows that the IIIa ∕ IIa ratio is generally < 0.59 in soils and 0.59–0.92 and > 0.92 in marine sediments with and without significant terrestrial inputs, respectively. Such disparity confirms the existence of two sources for brGDGTs, a terrestrial origin with lower IIIa ∕ IIa and a marine origin with higher IIIa ∕ IIa, which is likely attributed to a generally higher pH and the production of brGDGTs in cold deep water in marine waters. The application of the IIIa ∕ IIa ratio to the East Siberian Arctic Shelf proves it to be a sensitive source indicator for brGDGTs, which is helpful for accurate estimation of organic carbon source and paleoclimates in marine settings.
Desertification is a primary threat to crop farming, the livestock industry, and the eco-environment in northwestern China. Through field research and satellite imagery, it has been discovered that there are 4–5 sand belts in the shape of handclasps connecting major deserts in the Alxa Plateau region of northern China. These sand belts have been expanding for several decades. However, eolian sand transport between major deserts through these expanding sand belts is still underestimated. Identifying the source areas of eolian sands in deserts provide essential knowledge to prevent desertification. In this study, we collected samples from the northern Ulan Buh Desert (UBD), the Yamalik Desert (YD), and the Langshan Mountains and analyzed their REE contents in the <125 μm fraction. We compared REE geochemical characteristics of fine-grained sands in the UBD with other recently published REE data for potential source areas. Our findings indicate that the primary origins of fine-grained sands in the northern UBD are from the Qilian Mountains (QM) and Badain Jaran Desert (BJD), which are transported through the YD. Contributions from the Gobi-Altay Mountains to the north are relatively minor. The Langshan Mountains and Hawula Mountains are not considered as the primary sources of fine-grained sands in the UBD. In contrast, surface sediments in the southern UBD have a local mixture of the paleo-lacustrine deposits, the Gobi sediments, and minor external inputs from the BJD and QM. Our findings demonstrate that sand belts connecting these deserts play a crucial role in the eolian transport of fine-grained sands. Therefore, both the Chinese government and scientists should pay close attention to them in future efforts to combat desertification.