We present a complete set of all valid SWS full-scan 2.4-45.4 μm spectra processed and renormalized in as uniform a manner as possible. The processing produces a single spectrum for each observation from the 288 individual spectral segments, which are the most processed form available from the ISO archive. The spectra, and the programs used to create them, are available to the community on-line.

We have used the Infrared Spectrograph (IRS) on the Spitzer Space Telescope to obtain spectra of HD 100764, an apparently single carbon star with a circumstellar disk. The spectrum shows emission features from polycyclic aromatic hydrocarbons (PAHs) that are shifted to longer wavelengths than normally seen, as characteristic of ``class C'' systems in the classification scheme of Peeters et al. All seven of the known class C PAH sources are illuminated by radiation fields that are cooler than those which typically excite PAH emission features. The observed wavelength shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose that the class C PAH spectra are distinctive because the carbonaceous material has not been subjected to a strong ultraviolet radiation field, allowing relatively fragile aliphatic materials to survive.Comment: 11 pages (in emulateapj), 5 tables, 7 figures. Accepted for publication in Ap

It is critical for James Webb Space Telescope (JWST) science that instrumental units are converted to physical units. We detail the design of the JWST absolute flux calibration program that has the core goal of ensuring a robust flux calibration internal to and between all the science instruments for both point and extended source science. This program will observe a sample of calibration stars that have been extensively vetted based mainly on Hubble Space Telescope, Spitzer Space Telescope, and Transiting Exoplanet Survey Satellite observations. The program uses multiple stars of three different, well-understood types (hot stars, A dwarfs, and solar analogs) to allow for the statistical (within a type) and systematic (between types) uncertainties to be quantified. The program explicitly includes observations to calibrate every instrument mode, further vet the set of calibration stars, measure the instrumental repeatability, measure the relative calibration between subarrays and full frame, and check the relative calibration between faint and bright stars. For photometry, we have set up our calibration to directly support both the convention based on the band average flux density and the convention based on the flux density at a fixed wavelength.