According to the concept of fire life cycle assessment (LCA), a new type of intumescent flame retardant was designed and synthesized by chemically bonding chitosan, phosphorus pentoxide and melamine. The resultant compound, chitosan ethoxyl melamine phosphate (CEMP), was characterized by FTIR, ¹ H NMR, ³¹ P NMR, XRD and SEM. The performance of CEMP and organic montmorillonite (OMMT) was evaluated in the substrate of epoxy resin (EP) with limited oxygen index (LOI), UL-94, cone calorimetric test (CCT), TGA and TG-IR. As a result, intumescent flame retardant EP (EP3) containing 30.6% LOI and V-0 rating was prepared by adding 3 wt% OMMT and 15 wt% CEMP. The CCT results indicated that CEMP and OMMT reduced the peak of heat release rate (PHRR) to about one fourth that of pure EP and total heat release (THR), 1/2. Decomposition of EP and EP3 was traced from 100 to 600°C by TG-IR.

In this study, we report the synthesis of iron oxide nanoparticles (FeONPs) using micro-emulsion-hydrothermal method. By adjusting the synthesis temperature, we successfully produced FeO nanorods and nanospheres. In addition, the 2-octanol, and the surfactant cetyltrimethylammonium bromide served as a solvent in the synthesis process. Using iron nitrate hexahydrate as the salt precursor allowed for the formation of FeONPs with varied sizes, shapes and phases. The synthesized materials were extensively characterized using XRD, SEM, TEM, EDS, FTIR, and XPS techniques. However, the structural analysis revealed rhombohedral (hematite), and (magnetite) crystal structures in the materials synthesized at different temperature and durations, with particles ranged in size from 12 to 97 nm. More importantly, the magnetic characterization, performed with a vibrating sample magnetometer and SQUID magnetometer, indicated that the NPs showed not clear superparamagnetic behavior. In conclusion, this work demonstrates the synthesis of FeONPs with controlled size, shape and phase using microemulsion hydrothermal technique, with detailed characterization offering valuable insights into their magnetic and structural properties.