A hydrodynamic study of aluminum degassing by the rotating impeller technique was developed through experimental measurements obtained in a water physical model stirred with different impellers and air injection. The purpose of the work was to better understand degassing operation in molten aluminum through the analysis of the hydrodynamics of the system. Particle image velocimetry (PIV) was employed to measure flow patterns and turbulence characteristics of the ladle as a function of process and design variables, such as: a) impeller rotating speed (536 and 800 rpm), b) air flow rate (3 liters/min and 0 l/min), c) geometric design of the different impellers (impeller “A” made of a solid disc, impeller “B” with lateral nozzles and an impeller “C” with notches), where impellers “B” and “C” represent commercial designs. Impellers “B” and “C” presented similar flow behavior, with radial projection and pumping effect, while impeller “A” developed different flow patterns. By increasing the angular speed and the complexity of the impeller, stirring and turbulence increased through the entire ladle, while the vortex intensity grew. Gas injection modified the liquid flow patterns reducing the magnitude of the velocity in the liquid, and significantly increasing turbulence in the ladle.

This work examines the effect of nickel (Ni) and cobalt (Co) concentrations on wear resistance behavior of Cu-xNi-yCo-Cr-Si (x = 8−9 wt%, y = 1−2 wt%) and the zirconium (Zr) addition, in order to obtain an alloy with similar or better properties than the C17510 alloy. In this study, hardness and wear resistance mechanism behavior were associated with the microstructure evolution of these alloys with different aging strengthening conditions. Different heat treatments (HT) were applied to three alloys Cu-8Ni-2Co-1.6Cr-2Si wt% (L1), Cu-8.5Ni-1.5Co-1.6Cr-2Si wt% (L2) and Cu-9Ni-1Co-1.6Cr-2Si-0.18Fe-0.3Zr wt% (L3), the properties obtained were compared with C17510 alloy. Specimens were characterized by different metallographic techniques; the microstructural characterization was made with scanning electron microscopy (SEM) and revealed regions of dendritic morphologies. The solidification sequence is primary Cu dendrites and some phases in the interdendritic regions. The solution heat treatment decreased (ST) the Hardness Rockwell B (HRB) and wear rate resistance, and there was an increase with the first aging heat treatment (HT1) for each alloy. The most outstanding combination of properties was found for Cu-8.5Ni-1.5Co-1.6Cr-2Si wt% alloy (L2C3) with 100 ± 1 HRB and specific wear rate resistance of 1.2 × 10⁻⁴ mm³/Nm, after the first aging heat treatment.

Medium-entropy alloys (MEAs) allow the formation of different phases, generally in a solid-solution state, and compounds that favor obtaining alloys with properties superior to those of conventional alloys. In this study, medium-entropy CuNiSiCrCoTiNbx alloys were fabricated via melting in a vacuum induction furnace. The influence of the Nb addition (X = 0, 0.5 and 1 wt%) alloying elements on the microstructure, hardness, and wear resistance of the CuNiSiCrCoTiNb₀ (M1), CuNiSiCrCoTiNb_0.5 (M2), and CuNiCoCrSiTiNb₁ (M3) alloys were explored using X-ray diffraction (XRD), scanning electron microscopy (SEM), and a ball-on-disc tribometer, respectively. In general, the results indicated that the incorporation of Nb alloying element promoted the evolution of the microstructure, increased the hardness, and improvement of the wear resistance. The XRD and SEM findings demonstrate that higher Nb addition and aging heat treatment (AT) modification mainly favored the formation of dendritic regions and the precipitation of the Co₂Nb, Cr₃Si, and Ni₂Si phases, which promoted the refinement and strengthening of the microstructure. Significant increases in hardness were recorded: 11.95% increased, promoted by the addition of Nb before (E1) and after (E2, E3, and E4) the heat treatments. The maximum hardness values recorded were 92 ± 0.11 (AC) and 103 ± 0.5 HRB (AT-60 min) for the M3 alloy. The increase in hardness caused by Nb addition and aging heat treatments contributed to the dry sliding wear resistance response, decreasing material loss by 20%. This was related to the high concentration of precipitated phases rich in CoNb, CrSi, and NiSi with high hardness. Finally, the M3 alloy aged for 60 min exhibited the best specific wear rate behavior, with a material loss of 1.29 ${\mathrm{m}\mathrm{m}}^3$. The commercial Cu-Be C17510 alloy experienced a maximum hardness of 83.47 Hardness Rockwell B, HRB, and a high wear rate of 3.34 mm³.